TADDOL-Derived Phosphonites, Phosphites, and Phosphoramidites in Asymmetric Catalysis

被引：65
作者：
Lam, Hon Wai [1 ]
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
SYNTHESIS-STUTTGART | 2011年 / 13期
关键词：
asymmetric catalysis; phosphorus; ligands; enantioselectivity; TADDOL; ENANTIOSELECTIVE CONJUGATE ADDITION; C BOND FORMATION; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; CHIRAL PHOSPHORUS LIGANDS; CYCLIC MESO-ANHYDRIDES; KINETIC RESOLUTION; DIALKYLZINC REAGENTS; REDUCTIVE ALDOL; MONODENTATE PHOSPHORAMIDITE; ALKENYL ISOCYANATES;
D O I：
10.1055/s-0030-1260022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In metal-based asymmetric catalysis, desirable attributes for chiral ligands include low cost, simplicity of synthesis, and ease of variation to enable fine-tuning of a particular transformation. TADDOL-derived phosphonites, phosphites, and phosphoramidites constitute one family of chiral ligand that possesses these features. In recent times, these ligands have excelled in a wide range of catalytic asymmetric reactions. This review article summarizes progress in this area.
引用
收藏
页码：2011 / 2043
页数：33
相关论文
共 216 条
[1]   Synthesis of a tricyclic mescaline analogue by catalytic C-H bond activation [J].
Ahrendt, KA ;
Bergman, RG ;
Ellman, JA .
ORGANIC LETTERS, 2003, 5 (08) :1301-1303
[2]   ASYMMETRIC CATALYST [J].
AKABORI, S ;
SAKURAI, S ;
IZUMI, Y ;
FUJII, Y .
NATURE, 1956, 178 (4528) :323-324
[3]   Aryl-aryl bond formation by transition-metal-catalyzed direct arylation [J].
Alberico, Dino ;
Scott, Mark E. ;
Lautens, Mark .
CHEMICAL REVIEWS, 2007, 107 (01) :174-238
[4]   Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters [J].
Albicker, Martin R. ;
Cramer, Nicolai .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (48) :9139-9142
[5]   Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions [J].
Alexakis, A. ;
Backvall, J. E. ;
Krause, N. ;
Pamies, O. ;
Dieguez, M. .
CHEMICAL REVIEWS, 2008, 108 (08) :2796-2823
[6]   Biphenol-based ligands for Cu-catalyzed asymmetric conjugate addition [J].
Alexakis, A ;
Polet, D ;
Benhaim, C ;
Rosset, S .
TETRAHEDRON-ASYMMETRY, 2004, 15 (14) :2199-2203
[7]   Tandem copper-catalyzed enantioselective allylation-metathesis [J].
Alexakis, A ;
Croset, K .
ORGANIC LETTERS, 2002, 4 (23) :4147-4149
[8]  
Alexakis A, 2001, SYNLETT, P927
[9]   Asymmetric conjugate addition to alkylidene malonates [J].
Alexakis, A ;
Benhaim, C .
TETRAHEDRON-ASYMMETRY, 2001, 12 (08) :1151-1157
[10]  
Alexakis A, 1999, SYNLETT, P1811
12345678910