Highly Active Nickel-Based Catalyst for Hydrogen Evolution in Anion Exchange Membrane Electrolysis

被引：73

作者：

Faid, Alaa Y. ^{[1
]}

Barnett, Alejandro Oyarce ^{[2
]}

Seland, Frode ^{[1
]}

Sunde, Svein ^{[1
]}

机构：

[1] Norwegian Univ Sci & Technol, Dept Mat Sci & Engn, NO-7491 Trondheim, Norway

[2] SINTEF Ind, New Energy Solut Grp, Sustainable Energy Technol Dept, Trondheim, Norway

来源：

CATALYSTS | 2018年 / 8卷 / 12期

基金：

欧洲研究理事会;

关键词：

Nickel; HER; anion exchange membrane; electrolysis; CO-NI-B; WATER ELECTROLYSIS; HIGH-PERFORMANCE; ENERGY-STORAGE; ELECTROCATALYSTS; IMPEDANCE; NANOPARTICLES; DEGRADATION; ELECTRODES; OXIDATION;

D O I：

10.3390/catal8120614

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Anion exchange membrane (AEM) electrolysis is hampered by two main issues: stability and performance. Focusing on the latter, this work demonstrates a highly active NiMo cathode for hydrogen evolution in AEM electrolysis. We demonstrate an electrolyzer performance of 1 A cm(-2) at 1.9 V (total cell voltage) with a NiMo loading of 5 mg cm(-2) and an iridium black anode in 1 M KOH at 50 degrees C, that may be compared to 1.8 V for a similar cell with Pt at the cathode. The catalysts developed here will be significant in supporting the pursuit of cheap and environmentally friendly hydrogen fuel.

引用

页数：13

共 48 条

[11] Studies on catalytic behavior of Co-Ni-B in hydrogen production by hydrolysis of NaBH4 [J].

Fernandes, R. ;

Patel, N. ;

Miotello, A. ;

Filippi, M. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 298 (1-2) :1-6

[12] The influence of current constriction on the impedance of polarizable electrodes - Application to fuel cell electrodes [J].

Fleig, J ;

Maier, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (11) :L302-L305

[13] Kinetics of the hydrogen evolution on nickel in alkaline solution: new insight from rotating disk electrode and impedance spectroscopy analysis [J].

Franceschini, Esteban A. ;

Lacconi, Gabriela I. ;

Corti, Horacio R. .

ELECTROCHIMICA ACTA, 2015, 159 :210-218

[14] A mini review on nickel-based electrocatalysts for alkaline hydrogen evolution reaction [J].

Gong, Ming ;

Wang, Di-Yan ;

Chen, Chia-Chun ;

Hwang, Bing-Joe ;

Dai, Hongjie .

NANO RESEARCH, 2016, 9 (01) :28-46

[15]

Grond L., 2013, DNV KEMA, P1

[16] Co-Mo-B Nanoparticles as a non-precious and efficient Bifunctional Electrocatalyst for Hydrogen and Oxygen Evolution [J].

Gupta, S. ;

Patel, N. ;

Fernandes, R. ;

Hanchate, S. ;

Miotello, A. ;

Kothari, D. C. .

ELECTROCHIMICA ACTA, 2017, 232 :64-71

[17] Co-Ni-B nanocatalyst for efficient hydrogen evolution reaction in wide pH range [J].

Gupta, S. ;

Patel, N. ;

Fernandes, R. ;

Kadrekar, R. ;

Dashora, Alpa ;

Yadav, A. K. ;

Bhattacharyya, D. ;

Jha, S. N. ;

Miotello, A. ;

Kothari, D. C. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 192 :126-133

[18] Transient techniques for investigating mass-transport limitations in gas diffusion electrodes - II. Experimental characterization of the PEFC cathode [J].

Jaouen, F ;

Lindbergh, G ;

Wiezell, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :A1711-A1717

[19] Platinum group metal-free NiMo hydrogen oxidation catalysts: high performance and durability in alkaline exchange membrane fuel cells [J].

Kabir, Sadia ;

Lemire, Kenneth ;

Artyushkova, Kateryna ;

Roy, Aaron ;

Odgaard, Madeleine ;

Schlueter, Debbie ;

Oshchepkov, Alexandr ;

Bonnefont, Antoine ;

Savinova, Elena ;

Sabarirajan, Dinesh C. ;

Mandal, Pratiti ;

Crumlin, Ethan J. ;

Zenyuk, Iryna V. ;

Atanassov, Plamen ;

Serov, Alexey .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (46) :24433-24443

[20] Zero-Gap AlkalineWater Electrolysis Using Ion-Solvating Polymer Electrolyte Membranes at Reduced KOH Concentrations [J].

Kraglund, Mikkel Rykaer ;

Aili, David ;

Jankova, Katja ;

Christensen, Erik ;

Li, Qingfeng ;

Jensen, Jens Oluf .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (11) :F3125-F3131

← 1 2 3 4 5 →