Estimation of Physical and Nonlinear Optical Parameters of Vanadate Glasses

被引:0
作者
Yadav, Sandeep [1 ,2 ]
Kumari, Sonia [2 ]
Barala, Monika [2 ]
Mohan, Devendra [2 ]
Dhar, Rakesh [2 ]
Chaudhary, S. K. [1 ]
机构
[1] Baba Mast Nath Univ, Dept Phys, Rohtak, Haryana, India
[2] Guru Jambheshwar Univ Sci & Technol, Laser Lab, Dept Phys, Hisar, Haryana, India
来源
ADVANCES IN BASIC SCIENCES (ICABS 2019) | 2019年 / 2142卷
关键词
Semiconducting glasses; third order non-linear optical susceptibility; BASICITY; OXIDE; POLARIZABILITY;
D O I
10.1063/1.5122378
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Semiconducting Vanadate (V2O5 based) glass has plentiful application in the field of electrochemical batteries and optical switches.Theoretical investigation for density and molar volume are done for semiconducting glass with composition 60V(2)O(5).(40-x) ZnO.xMoO(3) (x=10,13,16,19,22). The density decreases from 4.1684.057g/cm(3) with increasing MoO3 content and an opposite behavior is observed for Molar volume. Using LorentzLorenz equation index of refraction is calculated and found to be very high (4.103 to 3.920) and Oxide ion polarizability varies little in the range 2.6935- 2.6908 angstrom(3). Using generalized Miller's rule, third order nonlinear optical susceptibility found to be very high 2.39x10(-6) to 1.61x10(-6) esu. and Nonlinear Index of Refraction varies from 2.194x10(-5) to 1.555x10(-5)esu.
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