Sequential click synthesis of hyperbranched polymers via the A2 + CB2 approach

被引:63
作者
Han, Jin [1 ]
Zhao, Bo [1 ]
Gao, Yanqin [1 ]
Tang, Aijin [1 ]
Gao, Chao [1 ]
机构
[1] Zhejiang Univ, Dept Polymer Sci & Engn, MOE Key Lab Macromol Synth & Functionalizat, Hangzhou 310003, Zhejiang, Peoples R China
基金
中国博士后科学基金; 高等学校博士学科点专项科研基金;
关键词
CONDENSING VINYL POLYMERIZATION; BB'(2) TYPE MONOMERS; DENDRITIC MACROMOLECULES; COPPER(I) CATALYSIS; AB(2) MONOMERS; YNE REACTIONS; CHEMISTRY; POLYTRIAZOLES; ENE; FUNCTIONALIZATION;
D O I
10.1039/c1py00235j
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Sequential thiol-ene and thiol-yne click chemistry via the A(2) + CB2 protocol is presented for simple, rapid, and scalable production of hyperbranched polymers, affording hyperbranched polythioetherynes with high molecular weight and high degree of branching.
引用
收藏
页码:2175 / 2178
页数:4
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