Spectroscopic properties of Ce3+-doped BaO-Gd2O3-Al2O3-B2O3-SiO2 glasses

被引：28

作者：

Zuo, Chenggang ^{[1
]}

Xiao, Anguo ^{[1
]}

Zhou, Zhihua ^{[2
]}

Chen, Yuandao ^{[1
]}

Zhang, Xiangyang ^{[1
]}

Ding, Xiang ^{[1
]}

Wang, Xiaobo ^{[1
]}

Ge, Qizhi ^{[3
]}

机构：

[1] Hunan Univ Arts & Sci, Coll Chem & Chem Engn, Changde 415000, Peoples R China

[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China

[3] Hunan Univ Arts & Sci, Coll Fu Rong, Changde 415000, Hunan, Peoples R China

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2016年 / 452卷

关键词：

Ce3+; Borosilicate glasses; Optical materials; Optical properties; Luminescence; Luminescence decay; OPTICAL-PROPERTIES; LUMINESCENCE; CERIUM;

D O I：

10.1016/j.jnoncrysol.2016.08.016

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Ce3+-doped BaO-Gd2O3-Al(2)O3-B2O3-SiO2 glasses with high density have been prepared by melt quenching method and the infrared transmission, UV-vis transmission, excitation, emission spectra and luminescence lifetime have been measured. The infrared transmission spectra, confirm there are [BO3] and [BO4] units for the borosilicate glasses. A broad absorption band is observed and the UV absorption edge shifts to a longer wavelength with the increase of SiO2/B2O3 ratio and Ce2O3 content. It exhibits an intense blue emission peaking around 404 nm which ascribes to 5d-4f electronic transition of Ce3+ ion under UV excitation. The emission intensity decreases and the emission maximum of Ce3+ ion shifts to longer wavelength with the increasing SiO2/B2O3 ratio and Ce2O3 content. The luminescence lifetime of Ce3+ ion in the borosilicate glasses is in an order of ns, which indicates the potential applications of Ce3+-doped BaO-Gd2O3-Al(2)O3-B2O3-SiO2 glasses in radiation detection. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：35 / 39

页数：5

共 37 条

[1] Blue emission spectrum of Ce3+:ZnO-B2O3-SiO2 optical glass
Annapurna, K
Dwivedi, RN
Kundu, P
Buddhudu, S
[J]. MATERIALS LETTERS, 2004, 58 (05) : 787 - 789
[2] Cerium doped heavy metal fluoride glasses, a possible alternative for electromagnetic calorimetry
Auffray, E
Bouttet, D
Dafinei, I
Fay, J
Lecoq, P
Mares, JA
Martini, M
Maze, G
Meinardi, F
Moine, B
Nikl, M
Pedrini, C
Poulain, M
Schneegans, M
Tavernier, S
Vedda, A
[J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1996, 380 (03) : 524 - 536
[3] Towards rare-earth clustering control in doped glasses
Auzel, F
Goldner, P
[J]. OPTICAL MATERIALS, 2001, 16 (1-2) : 93 - 103
[4] Optical properties of Ce3+-doped oxide glasses and correlations with optical basicity
Bei, Jiafang
Qian, Gujie
Liang, Xiaoluan
Yuan, Shuanglong
Yang, Yunxia
Chen, Guorong
[J]. MATERIALS RESEARCH BULLETIN, 2007, 42 (07) : 1195 - 1200
[5] Blasse G., 1994, GEN INTRO LUMINESCEN, V1, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1]
[6] STRUCTURE-PROPERTY RELATIONS IN LANTHANIDE BORATE GLASSES
CHAKRABORTY, IN
DAY, DE
LAPP, JC
SHELBY, JE
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1985, 68 (07) : 368 - 371
[7] Ultraviolet transparency and activator oxidation state of Ce3+-doped phosphate glasses
Chen, GR
Baccaro, S
Giorgi, R
Cecilia, A
Mihokova, E
Nikl, M
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2003, 326 : 339 - 342
[8] Luminescence of Ce3+/Tb3+ ions in lithium-magnesium aluminosilicate glasses
Chen, Yanping
Luo, Deli
Luo, Lizhu
Wang, Xiaoying
Tang, Tao
Luo, Wenhua
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2014, 386 : 124 - 128
[9] Luminescence and scintillation of Ce3+-doped high silica glass
Chewpraditkul, Weerapong
Shen, Yinglong
Chen, Danping
Yu, Bingkun
Prusa, Petr
Nikl, Martin
Beitlerova, Alena
Wanarak, Chalerm
[J]. OPTICAL MATERIALS, 2012, 34 (11) : 1762 - 1766
[10] Intense red photoluminescence from Mn2+-doped (Na+; Zn2+) sulfophosphate glasses and glass ceramics as LED converters
Da, Ning
Peng, Mingying
Krolikowski, Sebastian
Wondraczek, Lothar
[J]. OPTICS EXPRESS, 2010, 18 (03): : 2549 - 2557

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