Spectroscopic properties of Ce3+-doped BaO-Gd2O3-Al2O3-B2O3-SiO2 glasses

被引：29

作者：

Zuo, Chenggang ^{[1
]}

Xiao, Anguo ^{[1
]}

Zhou, Zhihua ^{[2
]}

Chen, Yuandao ^{[1
]}

Zhang, Xiangyang ^{[1
]}

Ding, Xiang ^{[1
]}

Wang, Xiaobo ^{[1
]}

Ge, Qizhi ^{[3
]}

机构：

[1] Hunan Univ Arts & Sci, Coll Chem & Chem Engn, Changde 415000, Peoples R China

[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China

[3] Hunan Univ Arts & Sci, Coll Fu Rong, Changde 415000, Hunan, Peoples R China

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2016年 / 452卷

关键词：

Ce3+; Borosilicate glasses; Optical materials; Optical properties; Luminescence; Luminescence decay; OPTICAL-PROPERTIES; LUMINESCENCE; CERIUM;

D O I：

10.1016/j.jnoncrysol.2016.08.016

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Ce3+-doped BaO-Gd2O3-Al(2)O3-B2O3-SiO2 glasses with high density have been prepared by melt quenching method and the infrared transmission, UV-vis transmission, excitation, emission spectra and luminescence lifetime have been measured. The infrared transmission spectra, confirm there are [BO3] and [BO4] units for the borosilicate glasses. A broad absorption band is observed and the UV absorption edge shifts to a longer wavelength with the increase of SiO2/B2O3 ratio and Ce2O3 content. It exhibits an intense blue emission peaking around 404 nm which ascribes to 5d-4f electronic transition of Ce3+ ion under UV excitation. The emission intensity decreases and the emission maximum of Ce3+ ion shifts to longer wavelength with the increasing SiO2/B2O3 ratio and Ce2O3 content. The luminescence lifetime of Ce3+ ion in the borosilicate glasses is in an order of ns, which indicates the potential applications of Ce3+-doped BaO-Gd2O3-Al(2)O3-B2O3-SiO2 glasses in radiation detection. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：35 / 39

页数：5

共 37 条

[1] Blue emission spectrum of Ce3+:ZnO-B2O3-SiO2 optical glass [J].

Annapurna, K ;

Dwivedi, RN ;

Kundu, P ;

Buddhudu, S .

MATERIALS LETTERS, 2004, 58 (05) :787-789

[2] Cerium doped heavy metal fluoride glasses, a possible alternative for electromagnetic calorimetry [J].

Auffray, E ;

Bouttet, D ;

Dafinei, I ;

Fay, J ;

Lecoq, P ;

Mares, JA ;

Martini, M ;

Maze, G ;

Meinardi, F ;

Moine, B ;

Nikl, M ;

Pedrini, C ;

Poulain, M ;

Schneegans, M ;

Tavernier, S ;

Vedda, A .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1996, 380 (03) :524-536

[3] Towards rare-earth clustering control in doped glasses [J].

Auzel, F ;

Goldner, P .

OPTICAL MATERIALS, 2001, 16 (1-2) :93-103

[4] Optical properties of Ce3+-doped oxide glasses and correlations with optical basicity [J].

Bei, Jiafang ;

Qian, Gujie ;

Liang, Xiaoluan ;

Yuan, Shuanglong ;

Yang, Yunxia ;

Chen, Guorong .

MATERIALS RESEARCH BULLETIN, 2007, 42 (07) :1195-1200

[5]

Blasse G., 1994, GEN INTRO LUMINESCEN, V1, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1]

[6] STRUCTURE-PROPERTY RELATIONS IN LANTHANIDE BORATE GLASSES [J].

CHAKRABORTY, IN ;

DAY, DE ;

LAPP, JC ;

SHELBY, JE .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1985, 68 (07) :368-371

[7] Ultraviolet transparency and activator oxidation state of Ce3+-doped phosphate glasses [J].

Chen, GR ;

Baccaro, S ;

Giorgi, R ;

Cecilia, A ;

Mihokova, E ;

Nikl, M .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2003, 326 :339-342

[8] Luminescence of Ce3+/Tb3+ ions in lithium-magnesium aluminosilicate glasses [J].

Chen, Yanping ;

Luo, Deli ;

Luo, Lizhu ;

Wang, Xiaoying ;

Tang, Tao ;

Luo, Wenhua .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2014, 386 :124-128

[9] Luminescence and scintillation of Ce3+-doped high silica glass [J].

Chewpraditkul, Weerapong ;

Shen, Yinglong ;

Chen, Danping ;

Yu, Bingkun ;

Prusa, Petr ;

Nikl, Martin ;

Beitlerova, Alena ;

Wanarak, Chalerm .

OPTICAL MATERIALS, 2012, 34 (11) :1762-1766

[10] Intense red photoluminescence from Mn2+-doped (Na+; Zn2+) sulfophosphate glasses and glass ceramics as LED converters [J].

Da, Ning ;

Peng, Mingying ;

Krolikowski, Sebastian ;

Wondraczek, Lothar .

OPTICS EXPRESS, 2010, 18 (03) :2549-2557

← 1 2 3 4 →