Organic-Inorganic Hybrids Assembled from Lanthanide and 1,4-Phenylenebis(phosphonate)

被引：31

作者：

Amghouz, Zakariae ^{[1
,2
]}

Garcia-Granda, Santiago ^{[1
,2
]}

Garcia, Jose R. ^{[1
,2
]}

Clearfield, Abraham ^{[3
]}

Valiente, Rafael ^{[4
]}

机构：

[1] Univ Oviedo CINN, Dept Quim Fis & Analit, Oviedo 33006, Spain

[2] Univ Oviedo CINN, Dept Quim Organ & Inorgan, Oviedo 33006, Spain

[3] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[4] Univ Cantabria, Dept Fis Aplicada, MALTA Consolider Team, E-39005 Santander, Spain

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 12期

关键词：

METAL PHOSPHONATE CHEMISTRY; RAY-POWDER STRUCTURES; STRONG BRONSTED ACIDS; HYDROTHERMAL SYNTHESIS; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; FRAMEWORKS; SYSTEM;

D O I：

10.1021/cg2008254

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of novel organic inorganic hybrids based on trivalent lanthanide (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho) and 1,4-phenylbis(phosphonate) formulated as Ln[O3P(C6H4)PO3H] has been obtained as single phases under hydrothermal conditions. In the praseodymium compound (Za1), single crystals have been obtained and the crystal structure has been determined. Za1 crystallizes in the monoclinic space group, C2/c, with a = 5.6060(4) angstrom, b = 20.251(7) angstrom, c = 8.2740(6) angstrom, beta = 108.52(1)degrees. All other compounds are isostructural to Za1 as confirmed by Rietveld refinement using X-ray powder diffraction data. Compounds are characterized by thermal analyses (TG-MS and SDTA), elemental analysis, IR spectra, and X-ray thermodiffraction analysis. Their visible photoluminescence properties are also discussed.

引用

页码：5289 / 5297

页数：9

共 52 条

[1] Uranyl Diphosphonates with Pillared Structures
Adelani, Pius O.
Albrecht-Schmitt, Thomas E.
[J]. INORGANIC CHEMISTRY, 2009, 48 (07) : 2732 - 2734
[2] Zirconium arene-phosphonates: Chemical and structural characterization of 2-naphthyl- and 2-anthracenylphosphonate systems
Amicangelo, JC
Leenstra, WR
[J]. INORGANIC CHEMISTRY, 2005, 44 (06) : 2067 - 2073
[3] [Anonymous], 1998, MULTIPURPOSE CRYSTAL
[4] Bellamy L.J., 1975, INFRA RED SPECTRA CO, VI
[5] BERDOWSKI PAM, 1984, J LUMIN, V29, P243, DOI 10.1016/0022-2313(84)90024-3
[6] BRANDENBURG K, 2007, DIAMOND VERSION 3 1
[7] Bruker, 2007, APEX2 SAINT
[8] SYNTHESIS OF LAYERED ZR(O3PCH2CH2COCL)2 FROM ZR(O3PCH2CH2COOH)2
BURWELL, DA
THOMPSON, ME
[J]. CHEMISTRY OF MATERIALS, 1991, 3 (01) : 14 - 17
[9] LAYERED METAL PHOSPHATES AND PHOSPHONATES - FROM CRYSTALS TO MONOLAYERS
CAO, G
HONG, HG
MALLOUK, TE
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (09) : 420 - 427
[10] Recent advances in metal phosphonate chemistry
Clearfield, A
[J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (02) : 268 - 278

← 1 2 3 4 5 6 →