Time-resolved fluorescence and UV absorbance study on Elaeis guineensis/oil palm leaf based carbon nanoparticles doped in nematic liquid crystals

被引:18
作者
Rastogi, Ayushi [1 ]
Pandey, Fanindra Pati [2 ]
Hegde, Gurumurthy [3 ]
Manohar, Rajiv [1 ]
机构
[1] Lucknow Univ, Phys Dept, Liquid Crystal Lab, Lucknow 226007, Uttar Pradesh, India
[2] Banaras Hindu Univ, Inst Sci, Phys Dept, Varanasi 221005, Uttar Pradesh, India
[3] BMS Coll Engn, Ctr Nanomat & Displays, Bengaluru 560019, India
关键词
Oil palm leaf based nanoparticles; Nematic liquid crystal; Photonic displays; Biosensor; RESONANCE ENERGY-TRANSFER; EMISSIVE STATES; QUANTUM DOTS; SURFACE; NITROGEN; PHOTOPHYSICS; EXPLORATION; DYNAMICS; ORIGIN;
D O I
10.1016/j.molliq.2020.112773
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Time resolved fluorescence measurement and UV absorbance study on oil palm leaf based nanoparticles (OPL) doped with nematic liquid crystal E 48 in 0.1, 0.2 and 0.3 wt/wt% concentration abbreviated as mixture 1 (MIX 1), mixture 2 (MIX 2) and mixture 3 (MIX 3) were conducted. OPL biomolecule loaded graphene oxide nematic E 48 liquid crystal systemhas been fabricated for biosensor application. The interaction of OPL nanoparticles with E 48 nematic liquid crystal having different concentration of nanoparticles has been explored. Pure nematic E 48 and its doped system have been examined by time- resolved fluorescence spectroscopy (TRFS) technique. Variation in the nanoparticles concentration strappingly affects the fluorescence emissions. Lack of Forster resonance energy transfer (FRET) was found in all composites. This manuscript unveils the purpose of a range of factors, such as dipolar interface between donor and acceptor molecules, nanoparticles orientation and its proximity distance that may be accountable for the non-appearance of FRET. Nematic nanoparticles doped system forms an antique composition of luminescent material even though the fluorescence characteristics of host are customized in the existence of nanoparticles by themolecular alignmentmodification. Variation in lifetimes of nematic nanoparticles doped system has been observed. These results find its applicability in photonic displays, photovoltaic devices, biosensors etc. (C) 2020 Published by Elsevier B.V.
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页数:13
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