Electrospun nanofiber mats coating-new route to flame retardancy

被引：24
作者：
Gallo, E. [1 ]
Fan, Z. [2 ,3 ]
Schartel, B. [1 ]
Greiner, A. [2 ,3 ]
机构：
[1] BAM Fed Inst Mat Res & Testing, D-12205 Berlin, Germany
[2] Univ Marburg, Dept Chem, D-35032 Marburg, Germany
[3] Univ Marburg, Sci Ctr Mat Sci, D-35032 Marburg, Germany
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 2011年 / 22卷 / 07期
关键词：
electrospinning; polyimide; nanofibers; fire retardancy; POLYMER; FIBERS;
D O I：
10.1002/pat.1994
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel route toward halogen-free fire retardancy of polymers through innovative surface coating is described. Nanofiber mats based on polyimide are deposited on PA66 through electrospinning. Scanning electron microscopy is used to characterize the nanofibers. Cone calorimeter tests were performed to evaluate the fire performance. Because of their low thermal conductivity, electrospun nanofiber mats act not only as sacrificial layers but also as a protective surface that delays ignition. The effect is influenced by the fiber diameters and the imidization. Copyright (C) 2011 John Wiley & Sons, Ltd.
引用
收藏
页码：1205 / 1210
页数：6
相关论文
共 14 条
[1]   New approach to flame retardancy using plasma assisted surface polymerisation techniques [J].
Bourbigot, S ;
Jama, C ;
Le Bras, M ;
Delobel, R ;
Dessaux, O ;
Goudmand, P .
POLYMER DEGRADATION AND STABILITY, 1999, 66 (01) :153-155
[2]  
Briers J., 2005, U.S. Patent, Patent No. [US 2005/0250908 Al, 2006131229]
[3]   Electrospinning of nanofibres: Towards new techniques, functions, and applications [J].
Dersch, Roland ;
Graeser, Martin ;
Greiner, Andreas ;
Wendorff, Joachim H. .
AUSTRALIAN JOURNAL OF CHEMISTRY, 2007, 60 (10) :719-728
[4]   Polymer nanofibers assembled by electrospinning [J].
Frenot, A ;
Chronakis, IS .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (01) :64-75
[5]   Electrospinning: A fascinating method for the preparation of ultrathin fibres [J].
Greiner, Andreas ;
Wendorff, Joachim H. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (30) :5670-5703
[6]   The use, design, synthesis, and properties of high performance/high temperature polymers: an overview [J].
Hergenrother, PM .
HIGH PERFORMANCE POLYMERS, 2003, 15 (01) :3-45
[7]   Characteristics of polyimide ultrafine fibers prepared through electrospinning [J].
Nah, C ;
Han, SH ;
Lee, MH ;
Kim, JS ;
Lee, DS .
POLYMER INTERNATIONAL, 2003, 52 (03) :429-432
[8]   Bending instability of electrically charged liquid jets of polymer solutions in electrospinning [J].
Reneker, DH ;
Yarin, AL ;
Fong, H ;
Koombhongse, S .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (09) :4531-4547
[9]   Nanometre diameter fibres of polymer, produced by electrospinning [J].
Reneker, DH ;
Chun, I .
NANOTECHNOLOGY, 1996, 7 (03) :216-223
[10]   Development of fire-retarded materials - Interpretation of cone calorimeter data [J].
Schartel, B. ;
Hull, T. R. .
FIRE AND MATERIALS, 2007, 31 (05) :327-354
12