Thermal conductivity of compressed H2O to 22 GPa: A test of the Leibfried-Schlomann equation

被引:71
作者
Chen, Bin [1 ]
Hsieh, Wen-Pin [2 ,3 ,4 ]
Cahill, David G. [3 ,4 ]
Trinkle, Dallas R. [3 ,4 ]
Li, Jie [5 ]
机构
[1] CALTECH, Div Geol & Planetary Sci, Pasadena, CA 91125 USA
[2] Univ Illinois, Dept Phys, Urbana, IL 61801 USA
[3] Univ Illinois, Mat Res Lab, Urbana, IL 61801 USA
[4] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA
[5] Univ Michigan, Dept Geol Sci, Ann Arbor, MI 48109 USA
来源
PHYSICAL REVIEW B | 2011年 / 83卷 / 13期
基金
美国国家航空航天局; 美国国家科学基金会;
关键词
MELTING CURVE; BULK MODULUS; DENSE H2O; FLUID H2O; ICE-VII; PRESSURE; SCATTERING; EXPANSIVITY; DEPENDENCE; ENERGY;
D O I
10.1103/PhysRevB.83.132301
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Leibfried-Schlomann (LS) equation, a commonly assumed model for the pressure dependence of thermal conductivity Lambda, is tested by measurements on compressed H2O using a combination of the time-domain thermoreflectance method with the diamond anvil cell technique. The thermal conductivity of ice VII increases by an order of magnitude between 2 and 22 GPa, reaching Lambda approximate to 25 W m(-1) K-1. Over a large compression range of approximate to 4%-33%, the LS equation describes the pressure dependence of Lambda of ice VII to better than 20%.
引用
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页数:4
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