Design and characterization of silver(I) azide coordination polymers based on 1,2-bis(4-pyridyl)ethane and phenazine

被引：12
|
作者：
Etaiw, Safaa El-din H. [1 ]
El-din, Ahmed S. Badr [1 ]
机构：
[1] Tanta Univ, Fac Sci, Dept Chem, Tanta, Egypt
来源：
TRANSITION METAL CHEMISTRY | 2011年 / 36卷 / 01期
关键词：
STRUCTURAL-CHARACTERIZATION; COMPLEXES; COPPER(I); LIGAND;
D O I：
10.1007/s11243-010-9428-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two silver(I) azide supramolecular coordination polymers (SCPs) with N-donor ligands have been synthesized and structurally characterized by physicochemical and spectroscopic methods; [AgN3.bpe] where bpe = 1,2-bis(4-pyridyl)ethane, 1, and [(AgN3)(2).phenz], 2, where phenz = phenazine. Syntheses were carried out in H2O/acetonitrile/NH3 media at room temperature. The topology of the bipodal ligands directs the silver azide building blocks to adopt different structures; 1D-chain, 1, or 1D-ribbon, 2. The azide groups exhibit an unusual bent structure with increasing bridging capability to adopt enough space for the bipodal ligands. The structure of SCP 2 contains the cyclic motif {Ag-2(mu(3)-N-3)(2)} to accommodate the voluminous phenz ligand. The emission spectra of the SCPs 1 and 2 display emission bands at 400-650 nm.
引用
收藏
页码：13 / 19
页数：7
相关论文
共 50 条
  • [1] Design and characterization of silver(I) azide coordination polymers based on 1,2-bis(4-pyridyl)ethane and phenazine
    Safaa El-din H. Etaiw
    Ahmed S. Badr El-din
    Transition Metal Chemistry, 2011, 36 : 13 - 19
  • [2] Coordination Compounds of Silver Methanesulfonate with Triphenylphosphine and 1,2-Bis(4-Pyridyl)ethane
    Yu. V. Kokunov
    V. V. Kovalev
    Yu. E. Gorbunova
    S. A. Kozyukhin
    G. A. Razgonyaeva
    Russian Journal of Coordination Chemistry, 2018, 44 : 103 - 108
  • [3] Coordination Compounds of Silver Methanesulfonate with Triphenylphosphine and 1,2-Bis(4-Pyridyl)ethane
    Kokunov, Yu. V.
    Kovalev, V. V.
    Gorbunova, Yu. E.
    Kozyukhin, S. A.
    Razgonyaeva, G. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2018, 44 (02) : 103 - 108
  • [4] 1,2-BIS(4-PYRIDYL)ETHANE
    IDE, S
    KARACAN, N
    TUFAN, Y
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 2304 - 2305
  • [5] 1,2-bis(4-pyridyl)ethane
    Ide, S.
    Karacan, N.
    Tufan, Y.
    Acta Crystallographica, Section C: Crystal Structure Communications, 1995, 51 (pt 11):
  • [6] Synthesis and characterization of coordination polymers with interpenetrated frameworks:: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M = Co, Mn
    Liao, JH
    Cheng, SH
    Tsai, HL
    Yang, CI
    INORGANICA CHIMICA ACTA, 2002, 338 : 1 - 6
  • [7] Network diversity and supramolecular isomerism in copper(II)/1,2-bis(4-Pyridyl)ethane coordination polymers
    Lazarou, Katerina N.
    Psycharis, Vassilis
    Terzis, Aris
    Raptopoulou, Catherine P.
    POLYHEDRON, 2011, 30 (06) : 963 - 970
  • [8] CuII and ZnII β-diketonate coordination polymers based on pyrimidin-2-amine, pyrazine and 1,2-bis(4-pyridyl)ethane
    Perdih, Franc
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 : 828 - 835
  • [9] Construction of lanthanide(III) coordination polymers with 1,2-bis(4-pyridyl) ethane-N, N′-dioxide and trans-1,2-bis(4-pyridyl)ethene-N, N′-dioxide
    Zhang, LP
    Lu, WJ
    Mak, TCW
    POLYHEDRON, 2004, 23 (01) : 169 - 176
  • [10] Luminescent coordination polymers for the VIS and NIR range constituting LnCl3 and 1,2-bis(4-pyridyl)ethane
    Dannenbauer, N.
    Matthes, P. R.
    Mueller-Buschbaum, K.
    DALTON TRANSACTIONS, 2016, 45 (15) : 6529 - 6540
12345