Crystallization and Magnetic Properties of Pr-Fe-B Alloys
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作者:
Gu, Yong
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机构:
Hangzhou Normal Univ, Qianjiang Coll, Hangzhou 310036, Peoples R ChinaHangzhou Normal Univ, Qianjiang Coll, Hangzhou 310036, Peoples R China
Gu, Yong
[1
]
Hua, Sihao
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机构:
Zhejiang Fangyuan Test Grp Co LTD, Hangzhou 310018, Peoples R ChinaHangzhou Normal Univ, Qianjiang Coll, Hangzhou 310036, Peoples R China
Hua, Sihao
[2
]
Pan, Minxiang
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机构:
China Jiliang Univ, Magnetism Key Lab Zhejiang Prov, Hangzhou 310018, Peoples R ChinaHangzhou Normal Univ, Qianjiang Coll, Hangzhou 310036, Peoples R China
Pan, Minxiang
[3
]
Huang, Xiani
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Zhejiang Fangyuan Test Grp Co LTD, Hangzhou 310018, Peoples R ChinaHangzhou Normal Univ, Qianjiang Coll, Hangzhou 310036, Peoples R China
Huang, Xiani
[2
]
机构:
[1] Hangzhou Normal Univ, Qianjiang Coll, Hangzhou 310036, Peoples R China
[2] Zhejiang Fangyuan Test Grp Co LTD, Hangzhou 310018, Peoples R China
[3] China Jiliang Univ, Magnetism Key Lab Zhejiang Prov, Hangzhou 310018, Peoples R China
In the present work, the thermal properties and crystallization process and kinetics of the as-spun Pr6Fe78B16 are thoroughly investigated. The activation energies E-c(x) of crystallization for the Pr2Fe14B phase increase rapidly first and then increase slowly to a maximum value 440 kJ/mol at the crystallization value of 40%, while the E-c(x) of Fe3B phase is mostly lower at the stage of crystallization and then increases gradually with the increase of crystallization fraction. Meanwhile, the enhanced magnetic properties (H-cj, 215 kA/m; M-r, 116 A m(2)/kg; and (BH)(max), 73.9 kJ/m(3)) have been obtained for the alloy with the annealing temperature at 660 degrees C. The results of magnetization reversal behavior show that a stronger exchange-coupling interaction between the hard and soft phases can be obtained by the proper annealing temperature.