Polymorphs with varying platinum(II)-thallium(I) interactions

被引：58
作者：
Stork, JR [1 ]
Olmstead, MM [1 ]
Balch, AL [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 18期
关键词：
D O I：
10.1021/ja050014a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
TlI[(C4H9N4)PtII(CN)2] forms a red, crystalline polymorph in which the ions are arranged to form an extended ⋯Pt⋯Tl⋯Pt⋯Tlmellip; chain (Pt⋯Tl distance, 3.0978(2) Å; Pt-Tl-Pt and Tl-Pt-Tl angles, (171.37(2)°) and a yellow polymorph in which dimers are connected by pairs of Pt⋯Tl interactions with a Pt⋯Tl distance of 3.0256(5) Å. Copyright © 2005 American Chemical Society.
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页码：6512 / 6513
页数：2
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