Magnetically Recoverable Iron Nanoparticle Catalyzed Cross-Dehydrogenative Coupling (CDC) between Two Csp3-H Bonds Using Molecular Oxygen

被引：80

作者：

Zeng, Tieqiang ^{[1
,2
]}

Song, Gonghua ^{[1
]}

Moores, Audrey ^{[2
]}

Li, Chao-Jun ^{[2
]}

机构：

[1] E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Inst Pesticides & Pharmaceut, Shanghai 200237, Peoples R China

[2] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

SYNLETT | 2010年 / 13期

基金：

加拿大自然科学与工程研究理事会;

关键词：

iron nanoparticles; oxygen; cross-coupling; C-C bond formation; SP(3) C-H; ONE-POT SYNTHESIS; OXIDATIVE ACTIVATION; RUTHENIUM HYDROXIDE; GLYCINE DERIVATIVES; DIRECT ALKYLATION; FUNCTIONALIZATION; HYDROGENATION; CHEMISTRY; ADJACENT;

D O I：

10.1055/s-0030-1258128

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative C-C bond formations between Csp(3)-H bond adjacent to nitrogen and Csp(3)-H bond of nitroalkanes are catalyzed efficiently by magnetically recoverable iron nanoparticles using oxygen. The catalyst can be magnetically removed and recycled easily for nine times without decreasing activity.

引用

页码：2002 / 2008

页数：7