Magnetically Recoverable Iron Nanoparticle Catalyzed Cross-Dehydrogenative Coupling (CDC) between Two Csp3-H Bonds Using Molecular Oxygen

被引：80
|
作者：
Zeng, Tieqiang [1 ,2 ]
Song, Gonghua [1 ]
Moores, Audrey [2 ]
Li, Chao-Jun [2 ]
机构：
[1] E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Inst Pesticides & Pharmaceut, Shanghai 200237, Peoples R China
[2] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
SYNLETT | 2010年 / 13期
基金：
加拿大自然科学与工程研究理事会;
关键词：
iron nanoparticles; oxygen; cross-coupling; C-C bond formation; SP(3) C-H; ONE-POT SYNTHESIS; OXIDATIVE ACTIVATION; RUTHENIUM HYDROXIDE; GLYCINE DERIVATIVES; DIRECT ALKYLATION; FUNCTIONALIZATION; HYDROGENATION; CHEMISTRY; ADJACENT;
D O I：
10.1055/s-0030-1258128
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidative C-C bond formations between Csp(3)-H bond adjacent to nitrogen and Csp(3)-H bond of nitroalkanes are catalyzed efficiently by magnetically recoverable iron nanoparticles using oxygen. The catalyst can be magnetically removed and recycled easily for nine times without decreasing activity.
引用
收藏
页码：2002 / 2008
页数：7
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