Bis(η5-cyclopentadienyl)(2-{[(2-methoxyphenyl)-imino]methyl}phenolato-κ3O,N,O′)terbium

被引：0
作者：
Minyaev, Mikhail E. [1 ,2 ]
Lyssenko, Konstantin A. [3 ]
Roitershtein, Dmitrii M. [1 ,2 ]
Nifant'ev, Ilya E. [2 ,3 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prospect, Moscow 119991, Russia
[2] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, 29 Leninsky Prospect, Moscow 119991, Russia
[3] Moscow MV Lomonosov State Univ, Chem Dept, 1 Leninskie Gory,Str Bldg 3, Moscow 119991, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷
基金：
俄罗斯科学基金会;
关键词：
lanthanide; terbium; bis(cyclopentadienyl); (methoxyphenyliminomethyl)phenolate; salicylimino; crystal structure; CRYSTAL-STRUCTURE; RARE-EARTH; COMPLEXES;
D O I：
10.1107/S2056989021013025
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The air- and moisture-sensitive title compound, [Tb(C5H5)(2)(C14H12NO2)], was synthesized from tris(cyclopentadienyl)(tetrahydrofuran)terbium and 2-{[(2-methoxyphenyl)imino]methyl}phenol. Each Tb atom is coordinated by two cyclopentadienyl ligands in an eta(5)-coordination mode and by one N and two 0 atoms of the organic ligand in a tridentate kappa O-3,N,O'-mode.
引用
收藏
页码：44 / +
页数：10
相关论文
共 26 条
  • [1] Bruker, 2016, APEX2 and SAINT
  • [2] Edelmann F.T., 1997, Synthetic Methods of Organometallic and Inorganic Chemistry (Herrman/Brauer), P34
  • [3] Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States
    Evans, William J.
    [J]. ORGANOMETALLICS, 2016, 35 (18) : 3088 - 3100
  • [4] THE ORGANOMETALLIC CHEMISTRY OF THE LANTHANIDE ELEMENTS IN LOW OXIDATION-STATES
    EVANS, WJ
    [J]. POLYHEDRON, 1987, 6 (05) : 803 - 835
  • [5] Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy
    Goodwin, Conrad A. P.
    Reta, Daniel
    Ortu, Fabrizio
    Liu, Jingjing
    Chilton, Nicholas F.
    Mills, David P.
    [J]. CHEMICAL COMMUNICATIONS, 2018, 54 (66) : 9182 - 9185
  • [6] The Cambridge Structural Database
    Groom, Colin R.
    Bruno, Ian J.
    Lightfoot, Matthew P.
    Ward, Suzanna C.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 : 171 - 179
  • [7] Physical Properties of Superbulky Lanthanide Metallocenes: Synthesis and Extraordinary Luminescence of [EuII(CpBIG)2] (CpBIG=(4-nBu-C6H4)5-Cyclopentadienyl)
    Harder, Sjoerd
    Naglav, Dominik
    Ruspic, Christian
    Wickleder, Claudia
    Adlung, Matthias
    Hermes, Wilfried
    Eul, Matthias
    Poettgen, Rainer
    Rego, Daniel B.
    Poineau, Frederic
    Czerwinski, Kenneth R.
    Herber, Rolfe H.
    Nowik, Israel
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (37) : 12272 - 12280
  • [8] Recent developments in organolanthanide polymerization catalysts
    Hou, ZM
    Wakatsuki, Y
    [J]. COORDINATION CHEMISTRY REVIEWS, 2002, 231 (1-2) : 1 - 22
  • [9] Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
    Krause, Lennard
    Herbst-Irmer, Regine
    Sheldrick, George M.
    Stalke, Dietmar
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2015, 48 : 3 - 10
  • [10] Synthesis and Crystal Structure of Er(NO3)3(HL)3 (HL = N-salicylidene-2-methoxyaniline)
    Li, Li
    Yuan, Fugen
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (07) : 994 - 998
123