Additivity of adiabatic compressibility with the size and geometry of the solute molecule

被引：16

作者：

Burakowski, Andrzej ^{[1
]}

Glinski, Jacek ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2008年 / 137卷 / 1-3期

关键词：

adiabatic compressibility coefficients; hydration; non-electrolytes in water; liquid structure;

D O I：

10.1016/j.molliq.2007.03.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It was shown for dilute aqueous solutions of few homologous series of organic non-electrolytes that the effect of solutes on compressibility decrease is directly linked to the length of their molecules and the groups, which are their constituents. The contributions of the groups - constituents of solute molecules - have been determined and discussed. It seems possible now to predict compressibility of aqueous solutions of organic non-electrolytes only from their structural formulae. (c) 2007 Elsevier B.V All rights reserved.

引用

页码：25 / 30

页数：6

共 47 条

[1] Volumetric properties of aqueous solutions of ethylene glycol oligomers at 25 degrees C [J].