Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy

被引：13

作者：

Demina, L. I. ^{[1
,2
]}

Kuz'mina, L. G. ^{[2
]}

Demin, S. V. ^{[1
,2
]}

Shokurova, N. A. ^{[1
]}

Zhilov, V. I. ^{[1
,2
]}

Tsivadze, A. Yu. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 11期

基金：

俄罗斯科学基金会;

关键词：

SPECTRAL-CONFORMATION ANALYSIS; ALKALI-METAL COMPLEXES; EXTRACTION; CHEMISTRY; SYSTEM;

D O I：

10.1134/S0036023617110031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H(2)OX, where X = Cl- (1), I- (2), (3), (5), and LiBF(4)B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1-4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.

引用

页码：1536 / 1543

页数：8

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