Sequential double second-order nonlinear optical switch by an acido-triggered photochromic cyclometallated platinum(II) complex

被引：58

作者：

Boixel, Julien ^{[1
]}

Guerchais, Veronique ^{[1
]}

Le Bozec, Hubert ^{[1
]}

Chantzis, Agisilaos ^{[2
]}

Jacquemin, Denis ^{[2
,3
]}

Colombo, Alessia ^{[4
]}

Dragonetti, Claudia ^{[4
,5
]}

Marinotto, Daniele ^{[5
]}

Roberto, Dominique ^{[4
,5
]}

机构：

[1] Univ Rennes 1, CNRS, Inst Sci Chim Rennes, UMR 6226, Campus Beaulieu, F-35042 Rennes, France

[2] Univ Nantes, CNRS, UMR 6230, CEISAM, F-44322 Nantes 3, France

[3] IUF, F-75005 Paris 5, France

[4] Univ Milan, UdR INSTM, Dipartimento Chim, I-20133 Milan, Italy

[5] CNR, ISTM, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 37期

基金：

欧洲研究理事会;

关键词：

RUTHENIUM COMPLEXES; METAL-COMPLEXES; CHROMOPHORES; HYPERPOLARIZABILITIES; DIARYLETHENE; DERIVATIVES; MOLECULES; EFFICIENT; MEMORIES; STRATEGY;

D O I：

10.1039/c5cc01893e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented DTE-based Pt(II) complex, 2(o), which stands as the first example of a sequential double nonlinear optical switch, induced first by protonation and next upon irradiation with UV light is presented.

引用

页码：7805 / 7808

页数：4

共 45 条

[1] Toward reliable density functional methods without adjustable parameters: The PBE0 model [J].

Adamo, C ;

Barone, V .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (13) :6158-6170

[2] Amphiphilic polyenic push-pull chromophores for nonlinear optical applications [J].

Alain, V ;

Blanchard-Desce, M ;

Ledoux-Rak, I ;

Zyss, J .

CHEMICAL COMMUNICATIONS, 2000, (05) :353-354

[3] Switching of molecular second-order polarisability in solution [J].

Asselberghs, I ;

Clays, K ;

Persoons, A ;

Ward, MD ;

McCleverty, J .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (19) :2831-2839

[4] Efficient photoswitching of the nonlinear optical properties of dipolar photochromic Zinc(II) complexes [J].

Aubert, Vincent ;

Guerchais, Veronique ;

Ishow, Elena ;

Hoang-Thi, Khuyen ;

Ledoux, Isabelle ;

Nakatani, Keitaro ;

Le Bozec, Hubert .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :577-580

[5] A "reverse interrupter": the novel molecular design of a fluorescent photochromic DTE-based bipyridine [J].

Aubert, Vincent ;

Ishow, Elena ;

Ibersiene, Fatima ;

Boucekkine, Abdou ;

Williams, J. A. Gareth ;

Toupet, Loic ;

Metivier, Remi ;

Nakatani, Keitaro ;

Guerchais, Veronique ;

Le Bozec, Hubert .

NEW JOURNAL OF CHEMISTRY, 2009, 33 (06) :1320-1323

[6] Spiropyrans and spirooxazines for memories and switches [J].

Berkovic, G ;

Krongauz, V ;

Weiss, V .

CHEMICAL REVIEWS, 2000, 100 (05) :1741-1753

[7] Second-Order NLO Switches from Molecules to Polymer Films Based on Photochromic Cyclometalated Platinum(II) Complexes [J].

Boixel, Julien ;

Guerchais, Veronique ;

Le Bozec, Hubert ;

Jacquemin, Denis ;

Amar, Anissa ;

Boucekkine, Abdou ;

Colombo, Alessia ;

Dragonetti, Claudia ;

Marinotto, Daniele ;

Roberto, Dominique ;

Righetto, Stefania ;

De Angelis, Roberta .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (14) :5367-5375

[8] Synthesis and photochromism of 1,2-bis(5-aryl-2-phenylethynylthien-3-yl)hexafluorocyclopentene derivatives [J].

Cai, Jianxin ;

Farhat, Amani ;

Tsitovitch, Pavel B. ;

Bodani, Vivek ;

Toogood, R. Daniel ;

Murphy, R. Scott .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2010, 212 (2-3) :176-182

[9] Design and Characterization of Molecular Nonlinear Optical Switches [J].

Castet, Frederic ;

Rodriguez, Vincent ;

Pozzo, Jean-Luc ;

Ducasse, Laurent ;

Plaquet, Aurelie ;

Champagne, Benoit .

ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (11) :2656-2665

[10] Long-range corrected hybrid density functionals with damped atom-atom dispersion corrections [J].

Chai, Jeng-Da ;

Head-Gordon, Martin .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (44) :6615-6620

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