First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene

被引：6

作者：

Oshima, Takumi ^{[1
]}

Mikie, Tsubasa ^{[1
]}

Ikuma, Naohiko ^{[1
]}

Yakuma, Hajime ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Suita, Osaka, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 09期

关键词：

HALOFORM INTERCALATED C-60; FACE AROMATIC INTERACTIONS; MOLECULAR TORSION BALANCE; SUPRAMOLECULAR CHEMISTRY; CHEMICAL-REACTIVITY; FULLERENES C-60; SOLID-STATE; SOFT ACIDS; C-70; SOLUBILITY;

D O I：

10.1039/c2ob06748j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first CH/pi solute-solvent interaction of C-60 was evidenced by the kinetic solvent effects in the Diels-Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k(2) with empirical solvent polarity and basicity parameters, E-T(30) and D-pi, respectively.

引用

页码：1730 / 1734

页数：5