Fe3+-sulfite complexation enhanced persulfate Fenton-like process for antibiotic degradation based on response surface optimization

被引：93
作者：
Yuan, Deling [1 ]
Zhang, Chen [1 ]
Tang, Shoufeng [1 ]
Sun, Mengting [1 ]
Zhang, Yating [1 ]
Rao, Yandi [1 ]
Wang, Zhibin [1 ]
Ke, Jun [2 ]
机构：
[1] Yanshan Univ, Hebei Key Lab Heavy Met Deep Remediat Water & Res, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Hebei, Peoples R China
[2] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430074, Peoples R China
来源：
SCIENCE OF THE TOTAL ENVIRONMENT | 2020年 / 727卷
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Persulfate; Sulfite; Complexation; Fenton-like process; Response surface optimization; Sulfamethoxazole degradation; ZERO-VALENT IRON; ACTIVATED PERSULFATE; HYDROGEN-PEROXIDE; OXIDATION PROCESS; WASTE-WATER; SULFAMETHOXAZOLE; REMOVAL; KINETICS; SULFITE; PEROXYMONOSULFATE;
D O I：
10.1016/j.scitotenv.2020.138773
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
To improve the cycle between Fe3+ and Fe2+ in persulfate (PS) Fenton-like system, sulfite (Na2SO3) was used as the iron complexing agent to enhance the degradation of sulfamethoxazole (SMX) antibiotic in water. Response surface methodology (RSM) was applied to regulate the operation parameters for the Fe3+/Na2SO3/PS synergistic system. Based on the RSM, the SMX could be completely degraded when the concentration of Fe3+, Na2SO3, and PS were 0.4, 0.5, and 2.5 mM, respectively. The result showed that the synergistic process represented a high Fe3+ utilization rate and SMX degradation efficiency. After 1 h reaction, 100.00% of SMX and 27.80% of total organic carbonwere removed under the ambient conditions containing the initial SMX concentration of 10 mu Mand initial pH of 5.96. Free radical masking and electron spin-resonance tests proved that hydroxyl radical (HO center dot) and oxysulfur radicals (SOx-center dot, x= 3, 4,5) were allplayedthesignificant role in the antibiotic removal, and the primary active radical was HO center dot. The SMX decomposition pathways based on the formed intermediates was proposed through the high-performance liquid chromatography andmass spectrumanalyses. The toxicity assessment prediction indicated that the toxicities of decomposed SMX byproducts were reduced after the coupling treatment. (C) 2020 Elsevier B.V. All rights reserved.
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页数：10
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