Fast adsorption kinetics of highly dispersed ultrafine nickel/carbon nanoparticles for organic dye removal

被引:73
作者
Kim, Taek-Seung [1 ]
Song, Hee Jo [1 ]
Dar, Mushtaq Ahmad [2 ]
Lee, Hack-Jun [1 ]
Kim, Dong-Wan [1 ]
机构
[1] Korea Univ, Sch Civil Environm & Architectural Engn, Seoul 136713, South Korea
[2] King Saud Univ, Adv Mfg Inst, Coll Engn, Ctr Excellence Res Engn Mat, Riyadh 11421, Saudi Arabia
基金
新加坡国家研究基金会;
关键词
Ni nanoparticle; Ultrafine; Magnetism; Dye; Fast adsorption; WASTE-WATER; NANOCOMPOSITES; EQUILIBRIUM; NICKEL; OXIDE;
D O I
10.1016/j.apsusc.2018.01.061
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Magnetic metal/carbon nano-materials are attractive for pollutant adsorption and removal. In this study, ultrafine nickel/carbon nanoparticles are successfully prepared via electrical wire explosion processing in ethanol media for the elimination of pollutant organic dyes such as Rhodamine B and methylene blue in aqueous solutions. High specific surface areas originating from both the nano-sized particles and the existence of carbon on the surface of Ni nanoparticles enhance dye adsorption capacity. In addition to this, the excellent dispersity of Ni/C nanoparticles in aqueous dye solutions leads to superior adsorption rates. The adsorption kinetics for the removal of organic dyes by Ni/C nanoparticles agree with a pseudo-second-order model and follow Freundlich adsorption isotherm behavior. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:364 / 370
页数:7
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