Biaryl-Bridged Salalen Ligands and Their Application in Titanium-Catalyzed Asymmetric Epoxidation of Olefins with Aqueous H2O2

被引：23

作者：

Xiong, Donglu ^{[1
,2
]}

Hu, Xiaoxue ^{[1
]}

Wang, Shoufeng ^{[1
]}

Miao, Cheng-Xia ^{[1
]}

Xia, Chungu ^{[1
]}

Sun, Wei ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 23期

基金：

中国国家自然科学基金;

关键词：

O ligands; Asymmetric catalysis; Epoxidation; Alkenes; Titanium; HIGHLY ENANTIOSELECTIVE EPOXIDATION; OXIDATIVE KINETIC RESOLUTION; HYDROGEN-PEROXIDE; ALLYLIC ALCOHOLS; AL(SALALEN) COMPLEX; SECONDARY ALCOHOLS; UNFUNCTIONALIZED OLEFINS; SALEN; HYDROPHOSPHONYLATION; ALDEHYDES;

D O I：

10.1002/ejoc.201100512

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of biaryl-bridged salalen ligands together with their titanium complexes have been designed and synthesized. The Ti complexes could serve as highly efficient catalysts for the asymmetric epoxidation of a wide range of olefins, giving the corresponding epoxides with high ee values.

引用

页码：4289 / 4292

页数：4

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