Facile One-Pot Synthesis and Optical Properties of Quinary Wurtzite Cu3ZnInSnS6 Nanocrystals

被引：3
|
作者：
Li, Dehui [1 ]
Zhang, Chen [1 ]
Zhang, Yajie [1 ]
Qi, Weichen [1 ]
Dong, Jinxiang [1 ]
Yang, Jing [1 ]
Qiu, Zhidong [1 ]
机构：
[1] Changchun Univ Chinese Med, Sch Pharmaceut Sci, 1035 Boshuo Rd, Changchun 130117, Peoples R China
来源：
NANO | 2016年 / 11卷 / 11期
关键词：
Quinary semiconductor; Cu3ZnInSnS6; nanocrystals; one-pot synthesis; optical properties; SEMICONDUCTOR NANOCRYSTALS; SOLAR-CELLS; CUINS2; NANOCRYSTALS; PHASE; CU2ZNSNS4; NANOPARTICLES; NANORODS; DEVICES;
D O I：
10.1142/S1793292016501307
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Nearly monodisperse bullet-like Cu3ZnInSnS6 (CZITS) nanocrystals with wurtzite structure were successfully synthesized through optimized noninjection method. The structure, composition, morphology and optical properties of CZITS nanocrystals were characterized by X-ray diffraction, energy dispersive spectrometry, transmission electron microscopy and UV-Vis-NIR absorption. Their suitable bandgap and photoresponsive behavior indicate a high potential application in the field of solar cells. The growth mechanism of the as-synthesized CZITS nanocrystals was preliminarily discussed. It was found that the formation of CZITS could be separated into two steps: nucleation of Cu7S4 and growth of the CZITS main body.
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页数：8
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