Study of Y zeolite catalysts for coal tar hydro-cracking in supercritical gasoline

被引:18
作者
Chang, Na [2 ]
Gu, Zhaolin [1 ]
Wang, Zanshe [1 ]
Liu, Zongkuan [2 ]
Hou, Xiongpo [2 ]
Wang, Juanping [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Human Settlements & Civil Engn, Xian 710049, Peoples R China
[2] Xi An Jiao Tong Univ, Sch Energy & Power Engn, Xian 710049, Peoples R China
关键词
Coal tar; Hydro-cracking; Catalyst selectivity; Zeolites; Supercritical gasoline; BED REACTOR; FUEL GAS; HYDROCRACKING; HDO;
D O I
10.1007/s10934-010-9413-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
For coal tar hydrocracking process in supercritical gasoline, it requires a new catalyst with high activity under low temperature conditions to improve the light oil yield. The effects of Mo-Co-Y and Mo-Ni-Y series catalyst on the light oil yield were investigated in this paper, and the coke deposition on catalyst and catalyst stability were also investigated. Experimental results show that the Mo-Co-Pd-Y zeolite catalyst with a suitable Co/(Co+Mo) atom ratio and calcination temperature could maximize the light oil yield, and the acid amount of the catalyst is closely related to its activity. Coke deposition on the Mo-Co-Pd-Y zeolite catalyst is very little and the catalyst remains high activity within used time of 8 h.
引用
收藏
页码:589 / 596
页数:8
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