Controlled/"Living" Radical Polymerization of Vinyl Acetate

被引：0
|
作者：
Tang, Huadong [1 ]
Radosz, Maciej [1 ]
Shen, Youqing [1 ]
机构：
[1] Univ Wyoming, Soft Mat Lab, Dept Chem & Petr Engn, Laramie, WY 82071 USA
来源：
CONTROLLED/LIVING RADICAL POLYMERIZATION: PROGRESS IN ATRP | 2009年 / 1023卷
关键词：
FRAGMENTATION CHAIN TRANSFER; POLY(VINYL ALCOHOL); STAR POLYMERS; BLOCK-COPOLYMERS; INITIATORS; ACRYLATES; MECHANISM; VERSATILE; KINETICS; CATALYST;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Controlled/"Living" radical polymerization (CRP) of vinyl acetate (VAc) via nitroxide-mediated polymerization (NMP), organocobalt-mediated polymerization, iodine degenerative transfer polymerization (DT), reversible radical addition-fragmentation chain transfer polymerization (RAFT), and atom transfer radical polymerization (ATRP) is summarized and compared with the ATRP of VAc catalyzed by copper halide/2,2' :6',2 ''-terpyridine. The new copper catalyst provides the first example of ATRP of VAc with clear mechanism and the facile synthesis of poly(vinyl acetate) and its block copolymers.
引用
收藏
页码：139 / 157
页数：19
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