(C5H5)2TiF2 and (C5H5)2ZrF2 as catalyst precursors for the dehydropolymerisation of Silanes

被引：28

作者：

Lunzer, F

Marschner, C

Landgraf, S

机构：

[1] Graz Tech Univ, Inst Anorgan Chem, A-8010 Graz, Austria

[2] Graz Tech Univ, Inst Phys & Theoret Chem, A-8010 Graz, Austria

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 568卷 / 1-2期

关键词：

titanocene; zirconocene; metallocenefluorides; dehydropolymerisation; polysilanes;

D O I：

10.1016/S0022-328X(98)00840-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(C5H5)2TiF(2) and (C5H5)(2)ZrF2 were found to be rapidly converted into catalytically-active species for the dehydrocoupling of silanes upon treatment with PhSiH3 or H2MeSiSiMeH2. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：253 / 255

页数：3

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