First synthesis of a unique dilead Schiff base complex

被引：54

作者：

Bhattacharyya, P ^{[1
]}

Parr, J ^{[1
]}

Ross, AT ^{[1
]}

Slawin, AMZ ^{[1
]}

机构：

[1] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 19期

关键词：

D O I：

10.1039/a806058d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the tripodal Schiff base ligand N[CH2CH2N=C(H)C6H3(OMe)-3-(OH)-2](3) (H3L) with lead(II) chloride in methanol in the presence of a base led to the bimetallic complex [Pb2L]Cl 1 in good yield; the cation was characterised crystallographically as the perchlorate salt 2, revealing dissimilar environments for the Pb(II) centres with one lead lying within the central cavity of (L)(3-) and the second bound externally to the three phenolate oxygens of the ligand.

引用

页码：3149 / 3150

页数：2

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