The effect of the substrate structure on the stereoselectivity in an asymmetric hydrogenation of unsaturated carboxylic acids over cinchonidine-modified palladium catalyst

被引：36

作者：

Sugimura, T ^{[1
]}

Watanabe, J ^{[1
]}

Okuyama, T ^{[1
]}

Nitta, Y ^{[1
]}

机构：

[1] Univ Hyogo, Himeji Inst Technol, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 09期

关键词：

D O I：

10.1016/j.tetasy.2005.03.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An enantiomeric ratio of 10: 1 (82% ee) was achieved for the first time in the hydrogenation of alpha,beta-tinsaturated acids with heterogeneous catalysts by designing the substrate structure to enhance the interaction with the catalyst, and to increase the intrinsic stereoselectivity. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1573 / 1575

页数：3

共 46 条

[41] ASYMMETRIC HYDROGENATION OF C=O DOUBLE-BOND WITH MODIFIED RANEY-NICKEL .24. EFFECT OF UNSATURATED COMPOUNDS ON ASYMMETRIC ACTIVITY OF CATALYST
NINOMIYA, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (08) : 2555 - +
[42] Effect of the substituent position on the enantioselective hydrogenation of methoxy-substituted 2,3-diphenylpropenoic acids over palladium catalyst
Szollosi, Gyoergy
Herman, Beata
Felfoldi, Karoly
Fulop, Ferenc
Bartok, Mihaly
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 290 (1-2) : 54 - 59
[43] Co-catalysis over a tri-functional ligand modified Pd-catalyst for hydroxycarbonylation of terminal alkynes towards α,β-unsaturated carboxylic acids
Yang, Da
Liu, Huan
Liu, Lei
Guo, Wen-Di
Lu, Yong
Liu, Ye
GREEN CHEMISTRY, 2019, 21 (19) : 5336 - 5344
[44] Heterogeneous asymmetric reactions.: Part 24.: Heterogeneous catalytic enantioselective hydrogenation of the C=N group over cinchona alkaloid modified palladium catalyst
Szöllösi, G
Kun, I
Bartók, M
CHIRALITY, 2001, 13 (10) : 619 - 624
[45] THE EFFECT OF CHIRAL SOLVENT AND VARIOUS KINDS OF CHIRAL ORGANIC SALTS ON THE ASYMMETRIC HYDROGENATION OF METHYL ACETOACETATE OVER AN IMPROVED TARTARIC ACID MODIFIED RANEY NICKEL CATALYST
Wang, Chaofeng
Zheng, Yunfeng
Cai, Shunli
Ma, Jiantai
Li, Rong
REACTION KINETICS AND CATALYSIS LETTERS, 2008, 95 (01): : 129 - 134
[46] The effect of chiral solvent and various kinds of chiral organic salts on the asymmetric hydrogenation of methyl acetoacetate over an improved tartaric acid modified Raney nickel catalyst
Chaofeng Wang
Yunfeng Zheng
Shunli Cai
Jiantai Ma
Rong Li
Reaction Kinetics and Catalysis Letters, 2008, 95 : 129 - 134

← 1 2 3 4 5 →