Gold(I) complexes with the ligand 1-thiolate-1,2-dicarba-closo-dodecaborate.: Crystal structure of [Au2(1-S-1,2-C2B10H11)2(μ-dppe)]

被引：16
作者：
Artigas, MM
Crespo, O
Gimeno, MC
Jones, PG
Laguna, A [1 ]
Villacampa, MD
机构：
[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 561卷 / 1-2期
关键词：
gold(I); o-carborane; thiolate;
D O I：
10.1016/S0022-328X(98)00500-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Neutral and anionic gold(I) mononuclear derivatives with the 1-thiolate-1,2-dicarba-closo-dodecaborat ligand of stoichiometries [Au(1-S-1,2-C2B10H11)L] and [Au(1-S-1,2-C2B10H11)(2)](-) have been synthesised. The complex [Au(1-S-1,2-C2B10H11)(AsPh3)] is a good starting material for the synthesis of the dinuclear gold(I) derivative [Au-2(1-S-1,2-C2B10H11)(2)(mu-PP)], where PP is a diphosphine. The compound [Au-2(1-S-1,2-C2B10H11)(PPh3)(2)]BF4 has also been prepared. The structure of the neutral complex [Au-2(1-S-1,2-C2B10H11)(2)(mu-dppe)] is confirmed by single-crystal X-ray diffraction. There are no short gold-gold interactions. (C) 1998 Elsevier Science S.A. All rights reserved.
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页码：1 / 6
页数：6
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