Alkoxymethylaluminum complexes with cyclopentadienyl ligand - Synthesis and characterization

被引:0
作者
Szumacher, S [1 ]
Leszczynska, K [1 ]
Kunicki, AR [1 ]
Madura, I [1 ]
Zachara, J [1 ]
机构
[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland
关键词
aluminum; cyclopentadienyl; alkoxide; multinuclear NMR;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of novel aluminum alkoxide derivatives, [Cp(Me)Al-mu-OR](2), (where R = Me 1, Et 2, Bu-i 3, (BuCH2)-Bu-t 4, Pr-i 5, Bu-t 6) has been prepared by reacting Me(Cl)AlOR with CpNa. All the compounds were characterized by multinuclear NMR, elemental analysis and molecular weight determination cryoscopically in benzene.
引用
收藏
页码:1773 / 1779
页数:7
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