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Alkoxymethylaluminum complexes with cyclopentadienyl ligand - Synthesis and characterization
被引:0
|作者:
Szumacher, S
[1
]
Leszczynska, K
[1
]
Kunicki, AR
[1
]
Madura, I
[1
]
Zachara, J
[1
]
机构:
[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland
关键词:
aluminum;
cyclopentadienyl;
alkoxide;
multinuclear NMR;
D O I:
暂无
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A series of novel aluminum alkoxide derivatives, [Cp(Me)Al-mu-OR](2), (where R = Me 1, Et 2, Bu-i 3, (BuCH2)-Bu-t 4, Pr-i 5, Bu-t 6) has been prepared by reacting Me(Cl)AlOR with CpNa. All the compounds were characterized by multinuclear NMR, elemental analysis and molecular weight determination cryoscopically in benzene.
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页码:1773 / 1779
页数:7
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