Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2

被引：53
作者：
Chen, Xi [1 ,2 ]
Sun, Jian [1 ]
Wang, Jinquan [1 ]
Cheng, Weiguo [1 ]
机构：
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, PR, Peoples R China
来源：
TETRAHEDRON LETTERS | 2012年 / 53卷 / 22期
关键词：
Cyclic carbonate; Ionic liquids; Polystyrene resin; Diethanolamine; CYCLIC CARBONATE SYNTHESIS; EFFICIENT CATALYSTS; DIOXIDE; EPOXIDES; CYCLOADDITION; COMPLEXES; IMMOBILIZATION; ACTIVATION; HALIDE; ROBUST;
D O I：
10.1016/j.tetlet.2012.03.058
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Polystyrene-bound diethanolamine based ionic liquids (PS-DHEEAB and PS-THEAB) were synthesized and applied for the chemical fixation of CO2 into cyclic carbonates without any additional co-catalyst and solvent. The effect of the catalysts with different number of hydroxyl group in the cation of the IL on the reaction was systematically investigated. Highest activity and selectivity were achieved in the presence of polystyrene supported diethanolamine ethyl bromide (PS-DHEEAB) in comparison with other catalysts employed. The catalyst was tough in stability and also found to be extended to a variety of terminal epoxides and aziridines. The relationship between high catalytic reactivity and the -OH functional groups was proposed. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2684 / 2688
页数：5
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