Facile synthesis, structure, and properties of Ag2S/Ag heteronanostructure

被引:22
|
作者
Sadovnikov, S. I. [1 ]
Gusev, A. I. [1 ]
机构
[1] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620990, Russia
基金
俄罗斯科学基金会;
关键词
Acanthite-argentite phase transformation; Silver sulfide; Silver; Heteronanostructure; Resistive switch; Memory device; SILVER; NANOCRYSTALLINE; METAL; AG; SEMICONDUCTOR; GROWTH;
D O I
10.1007/s11051-016-3592-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ag2S/Ag heteronanostructure has been produced by a simple one-stage chemical deposition from aqueous solutions of silver nitrate, sodium sulfide, and sodium citrate with the use of monochromatic light irradiation. For simultaneous synthesis of Ag2S and Ag nanoparticles, deposition has been performed from reaction mixtures with reduced sodium sulfide concentration. The size of Ag2S and Ag nanoparticles is 45-50 and 15-20 nm, respectively. It is established that in the contact layer between silver sulfide and silver, nonconducting alpha-Ag2S acanthite transforms into superionic beta-Ag2S argentite under the action of external electric field. The scheme of the operation of a resistive switch based on an Ag2S/Ag heteronanostructure is proposed. The UV-Vis optical absorption spectra of colloidal solutions of Ag2S/Ag heteronanostructures have been studied.
引用
收藏
页数:12
相关论文
共 50 条
  • [1] Facile synthesis, structure, and properties of Ag2S/Ag heteronanostructure
    S. I. Sadovnikov
    A. I. Gusev
    Journal of Nanoparticle Research, 2016, 18
  • [2] Structure and properties of Ag2S/Ag semiconductor/metal heteronanostructure
    Sadovnikov, Stanislav I.
    Gusev, Aleksandr I.
    BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY, 2016, 6 (06): : 1797 - 1804
  • [3] Ag2S/Ag Heteronanostructure
    Sadovnikov, S. I.
    Rempel', A. A.
    Gusev, A. I.
    JETP LETTERS, 2017, 106 (09) : 587 - 592
  • [4] Ag2S/Ag heteronanostructure
    S. I. Sadovnikov
    A. A. Rempel’
    A. I. Gusev
    JETP Letters, 2017, 106 : 587 - 592
  • [5] Structure and properties of nanoscale Ag2S/Ag heterostructure
    Gusev, A. I.
    Sadovnikov, S. I.
    MATERIALS LETTERS, 2017, 188 : 351 - 354
  • [6] Synthesis and Electrochemical Properties of Ag2S and Ag2S/Cu2S Crystals
    Pei, L. Z.
    Yang, L. J.
    Wang, J. F.
    Fan, C. G.
    Hu, J. L.
    E-JOURNAL OF SURFACE SCIENCE AND NANOTECHNOLOGY, 2010, 8 : 384 - 387
  • [7] Enhanced photocatalytic hydrogen evolution from aqueous solutions on Ag2S/Ag heteronanostructure
    Sadovnikov, S. I.
    Kozlova, E. A.
    Gerasimov, E. Yu.
    Rempel, A. A.
    Gusev, A. I.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (40) : 25258 - 25266
  • [8] Ag2S/ZnS nanocomposites: Synthesis, structure and optical properties
    Ramazanov, M. A.
    Nuriyeva, S. G.
    Shirinova, H. A.
    Karimova, A. H.
    Nuriyev, M. A.
    INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2021, 35 (03):
  • [9] Polymorphic Phase Transformations in Nanocrystalline Ag2S Silver Sulfide in a Wide Temperature Interval and Influence of Nanostructured Ag2S on the Interface Formation in Ag2S/ZnS Heteronanostructure
    Valeeva, Albina A.
    Sadovnikov, Stanislav, I
    Gusev, Aleksandr, I
    NANOMATERIALS, 2022, 12 (10)
  • [10] Synthesis and characterization of Ag2S and Ag2S/Ag2(S,Se) NIR nanocrystals
    Ruiz, Diego
    Mizrahi, Martin
    Santos, Harrisson D. A.
    Jaque, Daniel
    Jones, Callum M. S.
    Marques-Hueso, Jose
    Jacinto, Carlos
    Requejo, Felix G.
    Torres-Pardo, Almudena
    Gonzalez-Calbet, Jose M.
    Juarez, Beatriz H.
    NANOSCALE, 2019, 11 (18) : 9194 - 9200