Miscibility and specific interactions in polyacrylonitrile/poly(p-vinylphenol) blends

被引：0
|
作者：
Goh, SH [1 ]
Lee, SY
Yeo, YT
Zhou, X
Tan, KL
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore
[2] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 1999年 / 20卷 / 03期
关键词：
D O I：
10.1002/(SICI)1521-3927(19990301)20:3<148::AID-MARC148>3.0.CO;2-R
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A rare miscible polyacrylonitrile (PAN) blend system is reported. PAN is miscible with poly(p-vinylphenol) (PVPh) as shown by thermal and spectroscopic studies. A single glass transition temperature was found in each blend. Infrared spectroscopic studies showed that the hydroxyl band of PVPh and the cyano band of PAN shifted to lower frequencies upon blending, showing the existence of specific interactions between the two polymers. The involvement of cyano groups in specific interactions was further evidenced by the development of a high-binding-energy N1s peak in each blend from X-ray photoelectron spectroscopic studies.
引用
收藏
页码：148 / 151
页数：4
相关论文
共 50 条
  • [1] Miscibility and interactions in poly(methylthiomethyl methacrylate)/poly(p-vinylphenol) blends
    Yi, JZ
    Goh, SH
    Wee, ATS
    MACROMOLECULES, 2001, 34 (21) : 7411 - 7415
  • [2] Miscibility and specific interactions in poly(β-hydroxybutyrate-co-β-hydroxyvalerate) and poly(P-vinylphenol) blends
    Xing, PX
    Dong, LS
    Feng, ZL
    Feng, HQ
    EUROPEAN POLYMER JOURNAL, 1998, 34 (08) : 1207 - 1211
  • [3] Miscibility and interactions in poly(N-acryloylthiomorpholine)/poly(p-vinylphenol) blends
    Yi, JZ
    Goh, SH
    Wee, ATS
    MACROMOLECULES, 2001, 34 (13) : 4662 - 4665
  • [4] Miscibility of poly(1-vinylimidazole)/poly(p-vinylphenol) blends
    Polym Bull (Berlin), 2 (253):
  • [5] Miscibility of poly(1-vinylimidazole)/poly(p-vinylphenol) blends
    Goh, SH
    Lee, SY
    Tan, LIK
    POLYMER BULLETIN, 1996, 37 (02) : 253 - 257
  • [6] Miscibility and crystallization of poly(beta-hydroxybutyrate) and poly(p-vinylphenol) blends
    Xing, PX
    Dong, LS
    An, YX
    Feng, ZL
    Avella, M
    Martuscelli, E
    MACROMOLECULES, 1997, 30 (09) : 2726 - 2733
  • [7] Miscibility and interactions in blends and complexes of poly[2-(dimethylamino)ethyl methacrylate] with poly(p-vinylphenol)
    Huang, XD
    Goh, SH
    Lee, SY
    Zhao, ZD
    Wong, MW
    Huan, CHA
    MACROMOLECULES, 1999, 32 (13) : 4327 - 4331
  • [8] Miscibility and interactions in blends and complexes of poly(N-acryloyl-N′-methylpiperazine) with poly(p-vinylphenol)
    Liu, Y
    Goh, SH
    Lee, SY
    Huan, CHA
    MACROMOLECULES, 1999, 32 (06) : 1967 - 1971
  • [9] Miscibility and interactions in blends of two proton-donating polymers:: Poly(acrylic acid)/poly (p-vinylphenol) blends
    Li, XD
    Goh, SH
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (08) : 789 - 796
  • [10] Compatibility and specific interactions in poly(beta-hydroxybutyrate) and poly(p-vinylphenol) blends
    Xing, PX
    Dong, LS
    Feng, HQ
    An, YX
    Zhuang, YG
    Feng, ZL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (11): : 1813 - 1815
12345