Mechanistic Study of the Palladium-Catalyzed Stereoselective Cross-Coupling Reaction of 1,1-Dibromo-3,3,3-trifluoro-2-tosyloxypropene

被引：5

作者：

Shimizu, Masaki ^{[1
]}

Takeda, Vouhei ^{[1
]}

Hiyama, Tamejiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Chem Mat, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2011年 / 84卷 / 12期

关键词：

COMPLEXES;

D O I：

10.1246/bcsj.20110240

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We prepared a Pd complex by the oxidative addition of 1,1-dibromo-3,3,3-trifluoro-2-tosyloxypropene to [Pd-(PPh3)(4)]. The atomic distance between Pd and F in the complex was 2.95 angstrom. which was shorter than the sum of the van der Waals radii, suggesting that Pd F interaction played an important role in determining the stereochemical outcome of the Pd-catalyzed cross-coupling reaction of the propene.

引用

页码：1339 / 1341

页数：3

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