Methyl methacrylate oligomerically-modified clay and its poly(methyl methacrylate) nanocomposites

被引:30
作者
Zheng, XX [1 ]
Jiang, DD [1 ]
Wilkie, CA [1 ]
机构
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53233 USA
关键词
oligomerically-modified clay; nanocomposites; poly(methyl methacrylate); thermogravimetric analysis; cone calorimetry;
D O I
10.1016/j.tca.2005.06.006
中图分类号
O414.1 [热力学];
学科分类号
摘要
A methyl methacrylate oligomerically-modified clay was used to prepare poly(methyl methacrylate) clay nanocomposites by melt blending and the effect of the clay loading level on the modified clay and corresponding nanocomposite was studied. These nanocomposites were characterized by X-ray diffraction, transmission electron microscopy, thermogravimetric analysis and cone calorimetry. The results show a mixed intercalated/delaminated morphology with good nanodispersion. The compatibility between the methylacrylate-subsituted clay and poly(methyl methacrylate) (PMMA) are greatly improved compared to other oligomerically-modified clays. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:202 / 208
页数:7
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