Determination of methylparaben by differential pulse voltammetry using a glassy carbon electrode modified with polypyrrole

被引:17
|
作者
Madakbas, Seyfullah [1 ]
Kamiloglu, Senem [1 ]
Yetimoglu, Ece Kok [1 ]
机构
[1] Marmara Univ, Fac Art & Sci, Dept Chem, TR-34722 Istanbul, Turkey
关键词
differential pulse voltammetry; modified glassy carbon electrode; methylparaben; polypyrrole; PERFORMANCE LIQUID-CHROMATOGRAPHY; DOPED DIAMOND ELECTRODE; ELECTROCHEMICAL DETECTION; CONDUCTING POLYMER; METHYL PARABEN; SENSOR; COSMETICS; TYROSINE;
D O I
10.1134/S1061934815060155
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new modified glassy carbon electrode (GCE) based on a synthesized polypyrrole (PPy) was developed for the determination of methylparaben by differential pulse voltammetry (DPV). PPy was covalently immobilized on GCE surface using tetraethyl ammonium perchlorate (TEAP) and acetonitrile (ACN). Methylparaben was oxidized by differential pulse voltammetry and a peak was observed at 1.20 V. The calibration curve obtained with differential pulse voltammetry was linear in the concentration range from 0.01 to 5 mM methylparaben with a limit of detection of 8 x10(-3) mM and RSD of 0.11%. The improved method was applied to the determination of methylparaben in cream samples using the differential pulse voltammetry method.
引用
收藏
页码:725 / 730
页数:6
相关论文
共 50 条
  • [1] Determination of methylparaben by differential pulse voltammetry using a glassy carbon electrode modified with polypyrrole
    Seyfullah Madakbaş
    Senem Kamiloǧlu
    Ece Kök Yetimoǧlu
    Journal of Analytical Chemistry, 2015, 70 : 725 - 730
  • [2] Electrochemical determination of nonylphenol using differential pulse voltammetry based on a graphene-DNA-modified glassy carbon electrode
    Zeng, Lixuan
    Zhang, Aizhen
    Zhu, Xiaohua
    Zhang, Chuyi
    Liang, Yong
    Nan, Junmin
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2013, 703 : 153 - 157
  • [3] Simultaneous Determination of Caffeine and Pyridoxine in Energy Drinks using Differential Pulse Voltammetry at Glassy Carbon Electrode Modified with Nafion®
    Farag, Amir Shaaban
    Pravcova, Katerina
    Ceslova, Lenka
    Vytras, Karel
    Sys, Milan
    ELECTROANALYSIS, 2019, 31 (08) : 1511 - 1516
  • [4] Differential pulse voltammetry determination of salbutamol using disulfite tungsten/activated carbon modified glassy carbon electrode
    Do Mai Nguyen
    Thanh Tam Toan Tran
    Manh Dung Doan
    Van Thuan Le
    Quang Khieu Dinh
    CHEMOSPHERE, 2022, 303
  • [5] Determination of trimebutine in pharmaceuticals by differential pulse voltammetry at a glassy carbon electrode
    Adhoum, N
    Monser, L
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2005, 38 (04) : 619 - 623
  • [6] Electrochemical Determination of Butachlor by Differential Pulse Voltammetry (DPV) by an Electropolymerized Polypyrrole Molecular Imprinted Polymer (MIP) Modified Glassy Carbon Electrode (GCE)
    Li, Hao
    Tang, Jianshe
    Chen, Zhubin
    Xiang, Li
    ANALYTICAL LETTERS, 2023, 56 (17) : 2725 - 2737
  • [7] Determination of copper ions using a phytic acid/polypyrrole nanowires modified glassy carbon electrode
    Wang, Nan
    Dai, Hongxiu
    Wang, Donglei
    Ma, Houyi
    Lin, Meng
    MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2017, 76 : 139 - 143
  • [8] Determination of the herbicide paraquat using the new Ag-GO/CuO/GCE-modified glassy carbon electrode by differential pulse voltammetry
    Savary, Abdolrahman
    Yari, Abdollah
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2021, 68 (10) : 1987 - 1997
  • [9] The Determination of Riboflavin (Vitamin B2) Using Manganese Dioxide Modified Glassy Carbon Electrode by Differential Pulse Voltammetry
    Huang, De-Qian
    Wu, Hai
    Song, Chongfu
    Zhu, Qiangqiang
    Zhang, Hong
    Sheng, Liang-Quan
    Xu, Hua-Jie
    Liu, Zhao-Di
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2018, 13 (09): : 8303 - 8312
  • [10] Determination of Amlodipine in pharmaceutical formulations by differential-pulse voltammetry with a glassy carbon electrode
    Altiokka, G
    Dogrukol-Ak, D
    Tunçel, M
    Aboul-Enein, HY
    ARCHIV DER PHARMAZIE, 2002, 335 (2-3) : 104 - 108