Interrogation of electrocatalytic water oxidation mediated by a cobalt complex

被引：126

作者：

Wasylenko, Derek J. ^{[1
,2
]}

Palmer, Ryan D. ^{[1
,2
]}

Schott, Eduardo ^{[3
]}

Berlinguette, Curtis P. ^{[1
,2
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Calgary, Inst Sustainable Energy Environm & Econ, Calgary, AB T2N 1N4, Canada

[3] Univ Andres Bello, Dept Ciencias Quim, Santiago, Chile

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 15期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

CATALYST; PHOSPHATE;

D O I：

10.1039/c2cc16674g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Examination of the aqueous electrochemistry of a Co(II) complex bearing a pentadentate ligand suggests that the catalytic current corresponding to water oxidation is molecular in origin, and does not emanate exclusively from Co-oxide phases formed in situ.

引用

页码：2107 / 2109

页数：3

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