Palladium(II) complexes with Pd2S2 rings.: Synthesis and theoretical characterization of [Pd2(dppe)2(μ-S)2] and X-ray characterization of [Pd3(dppe)3(μ3-S)2]Cl2

被引：17

作者：

Capdevila, M

Clegg, W

Coxall, RA

González-Duarte, P

Hamidi, M

Lledós, A

Ujaque, G

机构：

[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

[2] Newcastle Univ, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

platinum complexes; sulfide complexes; crystal structures; theoretical calculations;

D O I：

10.1016/S1387-7003(98)00125-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of the dppe ligand and the line tuning of the experimental conditions has allowed isolation of [Pd-2(dppe)(2))(mu-S)(2)], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd-3(dppe)(3)(mu(3)-S)(2)]Cl-2, the X-ray structure of which is also reported. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：466 / 468

页数：3

相关论文

共 11 条

[1] To bend or not to bend:: Dilemma of the edge-sharing binuclear square planar complexes of d8 transition metal ions [J].

Aullon, G ;

Ujaque, G ;

Lledos, A ;

Alvarez, S ;

Alemany, P .

INORGANIC CHEMISTRY, 1998, 37 (04) :804-813

[2] CLUSTER INTERMEDIATES IN AN ORGANOMETALLIC SYNTHESIS OF PDTE [J].

BRENNAN, JG ;

SIEGRIST, T ;

STUCZYNSKI, SM ;

STEIGERWALD, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) :9233-9236

[3] CRYSTAL AND MOLECULAR-STRUCTURE AND P-31 AND PT-195 NMR-SPECTROSCOPY OF [PT3S2(PME2PH)6][BET4]2 - A TRINUCLEAR COMPLEX CONTAINING TRIPLY-BRIDGING SULFIDE LIGANDS [J].

BUSHNELL, GW ;

DIXON, KR ;

ONO, R ;

PIDCOCK, A .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (04) :696-702

[4] The first stable copper(II) complex containing four sulfide ligands:: synthesis and structural characterization of [Pt2(dppe)2(μ-S)2] and[Cu{Pt2(dppe)2(μ3-S)2}2]2+ [J].

Capdevila, M ;

Carrasco, Y ;

Clegg, W ;

Coxall, RA ;

González-Duarte, P ;

Lledós, A ;

Sola, J ;

Ujaque, G .

CHEMICAL COMMUNICATIONS, 1998, (05) :597-598

[5] SYNTHESES OF PHOTOACTIVE COMPLEXES - ELECTRONIC-SPECTRA, ELECTROCHEMISTRY, AND SCF-X-ALPHA-DV CALCULATIONS FOR BIS(PHOSPHINE)PALLADIUM OXALATE AND DITHIOOXALATE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF (DITHIOOXALATO-S,S')BIS(TRIMETHYLPHOSPHINE)PALLADIUM(II) AND (1,1-DITHIOOXALATO-S,S')BIS(MU-3-SULFIDO)-2,2,3,3-TETRAKIS(TRIMETHYLPHOSPHINE)-TRIANGULO-TRIPALLADIUM(II)S [J].

COWAN, RL ;

POURREAU, DB ;

RHEINGOLD, AL ;

GEIB, SJ ;

TROGLER, WC .

INORGANIC CHEMISTRY, 1987, 26 (02) :259-265

[6]

Frisch M.J., 1995, GAUSSIAN 94 REVISION

[7] Heteropolymetallic aggregates from [Pd-2(dppf)(2)(mu-S)(2). Bonding and structural analysis of [Ag2Pd2Cl2(dppf)(2)(mu(3)-S)(2)]center dot 4CH(2)Cl(2) [dppf equals Fe(C(5)H(4)PPh(2))(2)] - A flat {Pd2S2} core with two AgCl 'tails' [J].

Li, GM ;

Li, S ;

Tan, AL ;

Yip, WH ;

Mak, TCW ;

Hor, TSA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (23) :4315-4316

[8]

Liu H, 1997, POLYHEDRON, V16, P377

[9] SYNTHESIS AND CYCLIC VOLTAMMETRY OF TRINUCLEAR SULFIDO CLUSTERS OF NICKEL(II), PALLADIUM(II) AND PLATINUM(II) AND SELENIDO CLUSTERS OF NICKEL(II) WITH 1,2-BIS(DIPHENYL-PHOSPHINO)ETHANE, AND CRYSTAL-STRUCTURES OF SULFIDO AND SELENIDO CLUSTERS OF NICKEL(II) [J].

MATSUMOTO, K ;

SAIGA, N ;

TANAKA, S ;

OOI, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (05) :1265-1271

[10] FACILE CHALCOGENIDE ELIMINATION-REACTIONS - THE CRYSTAL-STRUCTURES OF [PT((PH2PO)2H)((PH2PSEO)2H)BULLET-1.25CHCL3 AND [PT3(PH2PCH2CH2PPH2)3S2][(PH2PSO)2H][OH]BULLET-0.5CH2CL2 [J].

PILKINGTON, MJ ;

SLAWIN, AMZ ;

WILLIAMS, DJ ;

WOOLLINS, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (15) :2425-2426