Very Fast, Ligand-Free and Aerobic Protocol for the Synthesis of 4-Aryl-Substituted Triphenylamine Derivatives

被引：26

作者：

Liu, Chun ^{[1
]}

Ni, Qijian ^{[1
]}

Qiu, Jieshan ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 16期

基金：

中国国家自然科学基金;

关键词：

Synthetic methods; Palladium; Boron; Cross coupling; Amines; COUPLING REACTIONS; CHARGE-TRANSFER; PALLADIUM NANOPARTICLES; SUZUKI REACTION; ARYL CHLORIDES; ORGANIC-DYES; ELECTROLUMINESCENCE; CHROMOPHORES; EMISSION; CATALYST;

D O I：

10.1002/ejoc.201100072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A fast, convenient and ligand-free protocol for the synthesis of a series of 4-aryl-substituted triphenylamine derivatives by a palladium-catalysed aerobic Suzuki reaction of aryl halides with [4-(diphenylamino)phenyl] boronic acid in aqueous iPrOH is described. Importantly, both aryl bromides and heteroaryl halides afforded good to excellent yields under mild conditions.

引用

页码：3009 / 3015

页数：7

共 34 条

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