Faclie synthesis and luminescence of hollow Eu3+-doped LaVO4 nanospheres

被引:7
作者
Tian, Li [1 ,2 ,3 ]
Zhao, Ruini [1 ]
Wang, Jinjing [1 ]
Sun, Qiliang [1 ]
Chen, Lin [1 ]
Xiao, Qiaoguo [1 ]
Liu, Shengli [1 ]
机构
[1] Hunan Univ Sci & Technol, Inst Chem & Chem Engn, Xiangtan 411201, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[3] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USA
关键词
Hydrothermal synthesis; Nanomaterials; LaVO4; Luminescence; NANOCRYSTALS; M-LAVO4;
D O I
10.1016/j.matlet.2015.05.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A facile and mild hydrothermal approach has been developed to prepare hollow t-LaVO4:Eu3+ nanospheres in Eu(NO3)(2) aqueous solution with solid LaCl3 center dot 7H(2)O and Na3VO4 as raw materials. The structure, morphology, composition and thermal behavior of LaVO4:Eu3+ nanospheres were studied by an X-ray diffractometer (XRD), a scanning electron microscope (SEM), an energy dispersive X-ray spectrometer instrument (EDS), a Fourier transform infrared spectrometer (FT-IR) and a differential thermal-thermogravimetric analyzer (DTA-TG). LaVO4:Eu3+ nanospheres hollow gradually with the increasing reaction time owing to Kirkendall effect. And hollow t-LaVO4:Eu3+ nanospheres show excellent red luminescence under 300 nm excitation, which could be of potential use in fabricating red-emitting nanolasers. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:101 / 104
页数:4
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