Copper(I) oxide catalyzed n-arylation of Azoles and Amines with arylboronic acid at room temperature under base-free conditions

被引：66

作者：

Sreedhar, Bojja ^{[1
]}

Venkanna, Gopaladasu T. ^{[1
]}

Kumar, Kota Balaji Shiva ^{[1
]}

Balasubrahmanyarn, Vura ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHESIS-STUTTGART | 2008年 / 05期

关键词：

copper(I) oxide; N-arylimidazoles; N-arylamines; N-arylation; heterogeneous catalyst;

D O I：

10.1055/s-2008-1032184

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Arylation of azoles and amines with arylboronic acids was efficiently carried out with heterogeneous copper(I) oxide in methanol at room temperature under base-free conditions. The products N-arylazoles and N-arylamines were isolated in good to excellent yields. A variety of arylboronic acids and amines were converted to the corresponding N-arylazoles and N-arylamines, demonstrating the versatality of the reaction.

引用

页码：795 / 799

页数：5

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