A solvent free method for preparation of β-amino alcohols by ring opening of epoxides with amines using MCM-22 as a catalyst

被引：33

作者：

Baskaran, Thangaraj ^{[1
]}

Joshi, Akanksha ^{[1
]}

Kamalakar, Gunda ^{[2
]}

Sakthivel, Ayyamperumal ^{[1
,3
]}

机构：

[1] Univ Delhi, Dept Chem, Inorgan Mat & Catalysis Lab, Delhi 110007, India

[2] SABIC Technol & Innovat Ctr, POB 42503, Riyadh 11551, Saudi Arabia

[3] Cent Univ Kerala, Dept Chem, Riverside Transit Campus, Nileshwar 671314, Kerala, India

来源：

APPLIED CATALYSIS A-GENERAL | 2016年 / 524卷

关键词：

MCM-22; beta-Amino alcohols; Epoxide ring opening; Zeolite; Heterogeneous catalyst; MESOPOROUS MOLECULAR-SIEVES; MG-AL HYDROTALCITE; ZEOLITE MCM-22; 2-DIMENSIONAL ZEOLITES; HYDROTHERMAL SYNTHESIS; EFFICIENT METHOD; PERSPECTIVES; OXIDATION; FRAMEWORK; NANOPARTICLES;

D O I：

10.1016/j.apcata.2016.05.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

beta-amino alcohols were synthesized at room temperature employing microporous MCM-22 zeolite as catalyst in an eco-friendly manner without using solvent. The zeolite MCM-22 showed promising activity for the conversion of primary and secondary amines into beta-amino alcohols under mild reaction conditions. The catalytic activity remains intact for three recycles. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：50 / 55

页数：6

共 46 条

[1] Recent Advances in Reactions of Alkylbenzenes Over Novel Zeolites: The Effects of Zeolite Structure and Morphology [J].

Al-Khattaf, Sulaiman ;

Ali, Syed A. ;

Aitani, Abdullah M. ;

Zilkova, Nadezda ;

Kubicka, David ;

Cejka, Jiri .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2014, 56 (04) :333-402

[2] Highly efficient ring opening reactions of epoxides with deactivated aromatic amines catalyzed by heteropoly acids in water [J].

Azizi, Najmedin ;

Saidi, Mohammad R. .

TETRAHEDRON, 2007, 63 (04) :888-891

[3] Progress on layered hydrotalcite (HT) materials as potential support and catalytic materials [J].

Baskaran, Thangaraj ;

Christopher, Jayaraj ;

Sakthivel, Ayyamperumal .

RSC ADVANCES, 2015, 5 (120) :98853-98875

[4] SBA-15 intercalated Mg-Al hydrotalcite: An environmental friendly catalyst for hydroisomerization of olefin [J].

Baskaran, Thangaraj ;

Christopher, Jayaraj ;

Ajithkumar, T. G. ;

Sakthivel, Ayyamperumal .

APPLIED CATALYSIS A-GENERAL, 2014, 488 :119-127

[5] Silicate anion intercalated cobalt-aluminium hydrotalcite (CoAl-HT-Si): a potential catalyst for alcohol oxidation [J].

Baskaran, Thangaraj ;

Kumaravel, Raju ;

Christopher, Jayaraj ;

Sakthivel, Ayyamperumal .

RSC ADVANCES, 2014, 4 (22) :11188-11196

[6] Silicate anion-stabilized layered magnesium-aluminium hydrotalcite [J].

Baskaran, Thangaraj ;

Kumaravel, Raju ;

Christopher, Jayaraj ;

Sakthivel, Ayyamperumal .

RSC ADVANCES, 2013, 3 (37) :16392-16398

[7] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[8] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].

Cavani, F. ;

Trifiro, F. ;

Vaccari, A. .

CATALYSIS TODAY, 1991, 11 (02) :173-301

[9] Zeolite-based materials for novel catalytic applications: Opportunities, perspectives and open problems [J].

Cejka, Jiri ;

Centi, Gabriele ;

Perez-Pariente, Joaquin ;

Roth, Wieslaw J. .

CATALYSIS TODAY, 2012, 179 (01) :2-15

[10] Scope and limitations of montmorillonite K 10 catalysed opening of epoxide rings by amines [J].

Chakraborti, AK ;

Kondaskar, A ;

Rudrawar, S .

TETRAHEDRON, 2004, 60 (41) :9085-9091

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