Mechanisms of Nickel-Catalyzed Cross-Coupling Reactions

被引:406
作者
Diccianni, Justin B. [1 ]
Diao, Tianning [1 ]
机构
[1] NYU, Dept Chem, 100 Washington Sq East, New York, NY 10003 USA
来源
TRENDS IN CHEMISTRY | 2019年 / 1卷 / 09期
关键词
GRIGNARD-REAGENTS; ALKYL-HALIDES; REDUCTIVE ELIMINATION; BOND FORMATION; ARYL HALIDES; COMPLEXES; ESTERS; NI(I); ACTIVATION; CYCLIZATION;
D O I
10.1016/j.trechm.2019.08.004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space of accessible structures and enabled newsynthetic disconnections. The unique properties of Ni catalysts facilitate the activation of traditionally inert substrates, tolerate alkyl coupling partners that undergo decomposition via b-hydride (b-H) elimination with Pd, and enable stereoconvergent cross-couplings. The radical pathways accessed by Ni catalysts have been merged with photoredox and electrochemical catalysis to achieve new reactivity. The growing utility of Ni catalysis is, in no small part, due to advances in our fundamental understanding of the properties of Ni catalysts and the mechanisms by which the reactions occur. This review highlights recent important contributions to the field with an emphasis on studies that have afforded mechanistic insight.
引用
收藏
页码:830 / 844
页数:15
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