Lipase-catalyzed enantioselective acylation in the ionic liquid solvent system: Reaction of enzyme anchored to the solvent

被引：189

作者：

Itoh, T ^{[1
]}

Akasaki, E ^{[1
]}

Kudo, K ^{[1
]}

Shirakami, S ^{[1
]}

机构：

[1] Okayama Univ, Fac Educ, Dept Chem, Okayama 7008530, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 03期

关键词：

D O I：

10.1246/cl.2001.262

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The lipase-catalyzed enantioselective acylation of allylic alcohols in an ionic liquid solvent was demonstrated: the reaction was significantly dependent on the counter anion of the imidazolium salt and good results were obtained when the reaction was carried out in [bmim]PF6 or [bmim]BF4 as solvent. We also first demonstrated that it was possible to repeatedly use the enzyme in the ionic liquid solvent system.

引用

页码：262 / 263

页数：2

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