Temperature dependence of the exciton gap in monocrystalline CuGaS2

被引:12
作者
Levcenco, S. [1 ]
Doka, S. [2 ]
Tezlevan, V. [1 ]
Marron, D. Fuertes [3 ]
Kulyuk, L. [1 ]
Schedel-Niedrig, T. [2 ]
Lux-Steiner, M. Ch. [2 ]
Arushanov, E. [1 ,2 ]
机构
[1] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
[2] Hahn Meitner Inst Berlin GmbH, D-14109 Berlin, Germany
[3] Univ Politecn Madrid, Inst Energia Solar ETSIT, E-28040 Madrid, Spain
关键词
Chalcopyrite; Photoluminescence Spectroscopy; OPTICAL-PROPERTIES; EPITAXIAL CUGAS2; SINGLE-CRYSTALS; PHOTOLUMINESCENCE; SI(111); ABSORPTION; AGGAS2; LAYERS; MODEL;
D O I
10.1016/j.physb.2010.05.037
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Single crystals of CuGaS2 have been grown by chemical vapour transport. Their near-band gap photoluminescence properties were investigated in the temperature range of 10-300 K. The variation of the exciton gap energy with temperature was studied by means of a three-parameter thermodynamic model, the Einstein model and the Passler model. Values of the band gap at T=0 K, of a dimensionless constant related to the electron-phonon coupling, and of an effective and a cut-off phonon energy have been estimated. It has also been found that the major contribution of phonons to the shift of E-g as a function of Tin CuGaS2 is mainly from optical phonons. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:3547 / 3550
页数:4
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