Rheology of a viscoelastic zwitterionic surfactant used in acid stimulation: Effects of surfactant and electrolyte concentration

被引:29
作者
Al-Sadat, W. [1 ]
Nasser, M. S. [2 ]
Chang, F. [3 ]
Nasr-El-Din, H. A. [4 ]
Hussein, I. A. [1 ]
机构
[1] King Fahd Univ Petr & Minerals, Dept Chem Engn, Dhahran, Saudi Arabia
[2] Qatar Univ, Coll Engn, Gas Proc Ctr, Doha, Qatar
[3] Schlumberger Dhahran Ctr Carbonate Res, Dhahran, Saudi Arabia
[4] Texas A&M, Dept Petr Engn, College Stn, TX USA
关键词
rheology; viscoelastic surfactant; zwitterionic; surfactant; well; stimulation; electrolyte; MICELLAR-SOLUTIONS; WORMLIKE MICELLES; SHEAR; ADDITIVES; BEHAVIOR; MODEL;
D O I
10.1016/j.petrol.2014.09.014
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Acid diversion systems play an important role in increasing the efficiency of the acid stimulation process. Viscoelastic surfactant (VES) based diverting systems have many advantages that make them preferred for well acid stimulation mainly due to their exceptional rheological characteristics. In this study, the rheological behavior of a zwitterionic surfactant (erucylamidopropyl carboxybetaine) used in the acid stimulation process is investigated through the steady-state and dynamic rheological measurements. The effects of surfactant and electrolyte concentrations and electrolyte type on the VES rheology are examined. It was found that the 7.5 wt% VES demonstrated the highest elastic strength in fresh water. The 22.0 wt% CaCl2 brine had the highest elastic strength when investigating the effect of the electrolyte concentration. The results also reveal that divalent cation electrolytes such as MgCl2 and CaCl2 increase the solution elasticity more than monovalent cation electrolytes such as NaCl, KCl, and NH4Cl. A strong correlation between the VES, electrolyte concentration, electrolyte type, and the efficiency of acid stimulation process is established. (c) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:341 / 349
页数:9
相关论文
共 37 条
[1]   A novel viscoelastic system from a cationic surfactant and a hydrophobic counterion [J].
Abdel-Rahem, R ;
Gradzielski, M ;
Hoffmann, H .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 288 (02) :570-582
[2]   Wormlike micelles in mixed surfactant solutions [J].
Acharya, Durga P. ;
Kunieda, Hironobu .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2006, 123 :401-413
[3]  
Chang F., 2006, U.S. Patent, Patent No. [7,119,050, 7119050]
[4]  
Chang F. F., 2002, U.S. Patent, Patent No. [6,399,546 B1, 6399546]
[5]  
Chang F.F., 2001, SOC PETR ENG ANN TEC
[6]   Improvement of Ca2+-tolerance by the introduction of EO groups for the anionic surfactants: Molecular dynamics simulation [J].
Chen, Yijian ;
Xu, Guiying .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2013, 424 :26-32
[7]  
Chuck Z., 2004, ANN TECHN C EXH HELD
[8]   Rheology, cryogenic transmission electron spectroscopy, and small-angle neutron scattering of highly viscoelastic wormlike micellar solutions [J].
Croce, V ;
Cosgrove, T ;
Maitland, G ;
Hughes, T ;
Karlsson, G .
LANGMUIR, 2003, 19 (20) :8536-8541
[9]   CHEMICAL DISSOLUTION OF A POROUS-MEDIUM BY A REACTIVE FLUID .1. MODEL FOR THE WORMHOLING PHENOMENON [J].
DACCORD, G ;
LENORMAND, R ;
LIETARD, O .
CHEMICAL ENGINEERING SCIENCE, 1993, 48 (01) :169-178
[10]  
Dubais A.M., 2004, SOC PETR ENG AS PAC