Guest encapsulation in a water-soluble molecular capsule based on ionic interactions

被引：147
作者：
Corbellini, F
Di Costanzo, L
Crego-Calama, M
Geremia, S
Reinhoudt, DN
机构：
[1] Univ Twente, Res Inst, Lab Supremol Chem & Technol, NL-7500 AE Enschede, Netherlands
[2] Univ Trieste, Dipartimento Sci Chim, Ctr Eccellenza Biocristallog, I-34127 Trieste, Italy
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 33期
关键词：
D O I：
10.1021/ja034535e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report on the synthesis and characterization of a water-soluble molecular capsule based on multiple ionic interactions. The assembly has been studied by means of 1H NMR, ESI-MS spectroscopy, and isothermal titration calorimetry (ITC), showing an association constant in water, Ka, of 3.3 × 104 M-1. The achieved water solubility of the system opens the possibility of using this supramolecular assembly for molecular recognition in pure water. Encapsulation studies have been performed and are reported in this Communication. Copyright © 2003 American Chemical Society.
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页码：9946 / 9947
页数：2
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