Design of efficient sergeant molecules for chiral induction in nano-porous supramolecular assemblies

被引：8
|
作者：
Minoia, Andrea [1 ]
Destoop, Iris [2 ]
Ghijsens, Elke [2 ]
De Feyter, Steven [2 ]
Tahara, Kazukuni [3 ]
Tobe, Yoshito [3 ]
Lazzaroni, Roberto [1 ]
机构：
[1] Univ Mons UMONS, B-7000 Mons, Belgium
[2] Katholieke Univ Leuven, Dept Chem, Div Mol & Nano Mat, B-3001 Leuven, Belgium
[3] Osaka Univ, Grad Sch Engn Sci, Div Frontier Mat Sci, Toyonaka, Osaka 5608531, Japan
来源：
RSC ADVANCES | 2015年 / 5卷 / 09期
基金：
欧洲研究理事会;
关键词：
MM3; FORCE-FIELD; MECHANICS; HYDROCARBONS; INTERFACE; NETWORKS;
D O I：
10.1039/c4ra11269e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study molecular modeling is used to investigate the transfer of chirality from the molecular level to homochiral, nano-porous 2D networks in self-assembled monolayers at the liquid/graphite interface. This allows proposing design rules for sergeant molecules for inducing chiral supramolecular assembly in nanoporous monolayers.
引用
收藏
页码：6642 / 6646
页数：5
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