Features of the synthesis of carbon nitride oxide (g-C3N4)O at urea pyrolysis

被引:50
作者
Kharlamov, Alexey [1 ]
Bondarenko, Marina [1 ]
Kharlamova, Ganna [2 ]
Gubareni, Nadezhda [1 ]
机构
[1] NASU, Frantsevich Inst Problems Mat Sci, Krzhyzhanovsky St 3, UA-03680 Kiev, Ukraine
[2] Taras Shevchenko Natl Univ Kiev, Volodymyrska St 64, UA-01601 Kiev, Ukraine
关键词
Carbon nitride oxide; Azagraphene; Pyrolysis; Urea; G-C3N4;
D O I
10.1016/j.diamond.2016.03.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
First from urea was synthesized carbon nitride oxide (g-C3N4)O which is formed in a vapor gas reactionary space and is deposited outside of a place of precursor localization. The reaction of urea conversion was investigated in an interval of temperatures 350-450 degrees C, but carbon nitride oxide is detected in the products of pyrolysis only at temperatures above 430 degrees C. Carbon nitride oxide is dissolved in water and at a reducing it by hydroquinone is formed reduced carbon nitride oxide consisting, as we believe, from azagraphene sheets. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:16 / 22
页数:7
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